Dissipation by a crystallization process

S Dorosz, T Voigtmann, T Schilling - Europhysics Letters, 2016 - iopscience.iop.org
S Dorosz, T Voigtmann, T Schilling
Europhysics Letters, 2016iopscience.iop.org
We discuss crystallization as a non-equilibrium process. In a system of hard spheres under
compression at a constant rate, we quantify the amount of heat that is dissipated during the
crystallization process. We interpret the dissipation as arising from the resistance of the
system against phase transformation. An intrinsic compression rate is identified that
separates a quasi-static regime from one of rapidly driven crystallization. In the latter regime
the system crystallizes more easily, because new relaxation channels are opened, at the …
Abstract
We discuss crystallization as a non-equilibrium process. In a system of hard spheres under compression at a constant rate, we quantify the amount of heat that is dissipated during the crystallization process. We interpret the dissipation as arising from the resistance of the system against phase transformation. An intrinsic compression rate is identified that separates a quasi-static regime from one of rapidly driven crystallization. In the latter regime the system crystallizes more easily, because new relaxation channels are opened, at the cost of forming a higher fraction of non-equilibrium crystal structures. We rationalize the change in the crystallization mechanism by analogy with shear thinning, in terms of a kinetic competition between near-equilibrium relaxation and external driving.
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