Pleochroism or dichroism is the change in color evident as the mineral is rotated under plane-polarized light.
The primary cause of dichroism or pleochroism in minerals is due to adsorption of particular wavelengths of light. This selective adsorption of certain wavelengths of light causes the transmitted light to appear colored. This color is a function of the thickness and the particular chemical and crystallographic nature of the mineral.
If the adsorption of particular wavelengths of light differs according to the optical path, the phenomena of pleochroism is evident. This is observable in plane-polarized light when the polarizers select the light exiting from the mineral. This color depends on which optical path is viewed.
Pleochroic colors are observed and recorded in the mineral data and are generally diagnostic of the particular mineral.
Pleochroism | Crystallography |
None (no variation in color) | Isotropic minerals are always dark under crossed polarizers. Anisotropic minerals are not. If no color variation is observed on rotation under plane-polarized light then the mineral is non-pleochroic. |
Dichroic (two colors observed) | Dichroic minerals are generally always hexagonal, trigonal, or tetragonal. |
Pleochroic (three color observed) | Pleochroic minerals are generally always orthorhombic, monoclinic, or triclinic. |
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