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Helium: Difference between revisions - Wikipedia
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* {{cite journal |last1=Clève |title=Sur la densité de l'hélium |journal=Comptes rendus hebdomadaires des séances de l'Académie des sciences |date=1895 |volume=120 |page=1212 |url=https://babel.hathitrust.org/cgi/pt?id=mdp.39015035451122&view=1up&seq=1226&skin=2021 |trans-title=On the density of helium |language=French}}</ref><ref>{{Cite journal|title = Das Atomgewicht des Heliums|trans-title = The atomic weight of helium|author = Langlet, N. A.|journal = Zeitschrift für Anorganische Chemie|volume = 10|issue = 1| pages = 289–292|date = 1895|url=https://books.google.com/books?id=sHcWAAAAIAAJ&pg=PA289|doi =10.1002/zaac.18950100130|language= de}}</ref><ref name="nbb" /><ref>{{cite book |last1=Weaver |first1=E.R. |title=Circular of the Bureau of Standards No. 81: Bibliography of Scientific Literature Relating to Helium |date=1919 |page=6 |publisher=U.S. Government Printing Office |location=Washington, D.C., USA |url=https://nvlpubs.nist.gov/nistpubs/Legacy/circ/nbscircular81.pdf}}</ref> Helium was also isolated by American geochemist [[William Francis Hillebrand]] prior to Ramsay's discovery, when he noticed unusual spectral lines while testing a sample of the mineral uraninite. Hillebrand, however, attributed the lines to [[nitrogen]].<ref>Hillebrand (1890) [https://babel.hathitrust.org/cgi/pt?id=uc1.b2968310&view=1up&seq=511 "On the occurrence of nitrogen in uraninite and on the composition of uraninite in general,"] ''Bulletin of the U.S. Geological Survey'', no. 78, pp. 43–79.</ref> His letter of congratulations to Ramsay offers an interesting case of discovery, and near-discovery, in science.<ref>{{Cite book|last=Munday|first=Pat|author-link=Pat Munday|date=1999|title=Biographical entry for W.F. Hillebrand (1853–1925), geochemist and U.S. Bureau of Standards administrator in American National Biography|editor=John A. Garraty|editor2=Mark C. Carnes|volume=10–11|publisher=Oxford University Press|pages= 808–9; 227–8|title-link=American National Biography}}</ref>
 
In 1907, [[Ernest Rutherford]] and [[Thomas Royds]] demonstrated that [[alpha particle]]s are helium [[atomic nucleus|nuclei]], by allowing the particles to penetrate the thin, glass wall of an [[evacuated tube]], then creating a discharge in the tube, to study the spectrum of the new gas inside.<ref>{{Cite journal| doi = 10.1080/14786440808636511| title = XXIV.Spectrum of the radium emanation| journal = Philosophical Magazine| series = series 6| volume = 16| issue = 92| pages = 313–317| year = 1908| last1 = Rutherford| first1 = E.| last2 = Royds| first2 = T.| url = https://babel.hathitrust.org/cgi/pt?id=umn.31951000614205r;view=1up;seq=349}}</ref> In 1908, helium was first liquefied by Dutch physicist [[Heike Kamerlingh Onnes]] by cooling the gas to less than {{convert|5|K|C F}}.<ref>Onnes, H. Kamerlingh (1908) [https://web.archive.org/web/20180809111624/https://babel.hathitrust.org/cgi/pt?id=uva.x002433831;view=1up;seq=309 "The liquefaction of helium,"] ''Communications from the Physical Laboratory at the University of Leiden'', '''9''' (108) : 1–23.</ref><ref>{{Cite journal|title = Little cup of Helium, big Science |author = van Delft, Dirk |journal = Physics Today |url = http://www-lorentz.leidenuniv.nl/history/cold/VanDelftHKO_PT.pdf |pages = 36–42 |date = 2008 |access-date = 2008-07-20|archive-url = https://web.archive.org/web/20080625064354/http://www-lorentz.leidenuniv.nl/history/cold/VanDelftHKO_PT.pdf |archive-date = June 25, 2008|url-status=dead|bibcode = 2008PhT....61c..36V|volume = 61|doi = 10.1063/1.2897948|issue = 3}}</ref> He tried to solidify it, by further reducing the temperature, but failed, because helium does not solidify at atmospheric pressure. Onnes' student [[Willem Hendrik Keesom]] was eventually able to solidify 1&nbsp;cm<sup>3</sup> of helium in 1926 by applying additional external pressure.<ref>See:
* Preliminary notice: Keesom, W. H. (17 July 1926) Letters to the Editor: "Solidification of helium," ''Nature'', '''118''' : 81.
* Preliminary notice: Keesom, W. H. (1926) [https://archive.org/stream/ComptesRendusAcademieDesSciences0183/ComptesRendusAcadmieDesSciences-Tome183-Juillet-dcembre1926#page/n25/mode/2up "L'hélium solidifié,"] {{Webarchive|url=https://web.archive.org/web/20161022075647/https://archive.org/stream/ComptesRendusAcademieDesSciences0183/ComptesRendusAcadmieDesSciences-Tome183-Juillet-dcembre1926#page/n25/mode/2up |date=2016-10-22 }} ''Comptes rendus'' ... , '''183''' : 26.