Undecane
![]() | |
![]() | |
![]() | |
Names | |
---|---|
Preferred IUPAC name
Undecane[1] | |
Identifiers | |
3D model (JSmol)
|
|
1697099 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.013.001 |
EC Number |
|
MeSH | undecane |
PubChem CID
|
|
RTECS number |
|
UNII | |
UN number | 2330 |
CompTox Dashboard (EPA)
|
|
| |
| |
Properties | |
C11H24 | |
Molar mass | 156.313 g·mol−1 |
Appearance | Colorless liquid |
Odor | Gasoline-like to Odorless |
Density | 740 g/L |
Melting point | −26 °C (−15 °F; 247 K) |
Boiling point | 196 °C (385 °F; 469 K) |
log P | 6.312 |
Vapor pressure | 55 Pa (at 25 °C)[2] |
Henry's law
constant (kH) |
5.4 nmol Pa−1 kg−1 |
-131.84·10−6 cm3/mol | |
Refractive index (nD)
|
1.417 |
Thermochemistry | |
Heat capacity (C)
|
345.05 J K−1 mol−1 |
Std molar
entropy (S⦵298) |
458.15 J K−1 mol−1 |
Std enthalpy of
formation ( |
−329.8–−324.6 kJ mol−1 |
Std enthalpy of
combustion ( |
−7.4339–−7.4287 MJ mol−1 |
Hazards | |
GHS labelling: | |
![]() ![]() | |
Danger | |
H304, H315, H319, H331, H335 | |
P261, P301+P310, P305+P351+P338, P311, P331 | |
NFPA 704 (fire diamond) | |
Flash point | 60.0 °C (140.0 °F; 333.1 K) |
240 °C (464 °F; 513 K) | |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
|
> 2000 mg/kg (rat, oral) > 5000 mg/kg (rat, dermal) |
LC50 (median concentration)
|
> 20 mg/L (rat, 8 hours) |
Safety data sheet (SDS) | Fisher Scientific |
Related compounds | |
Related alkanes
|
|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
Undecane (also known as hendecane) is a liquid alkane hydrocarbon with the chemical formula CH3(CH2)9CH3. It is used as a mild sex attractant for various types of moths and cockroaches, and an alert signal for a variety of ants.[3] It has 159 isomers.[4]
Undecane may also be used as an internal standard in gas chromatography when working with other hydrocarbons. Since the boiling point of undecane (196 °C) is well known, it may be used as a comparison for retention times in a gas chromatograph for molecules whose structure has been freshly elucidated. For example, if one is working with a 50 m crosslinked methyl silicone capillary column with an oven temperature increasing slowly, beginning around 60 °C, an 11-carbon molecule like undecane may be used as an internal standard to be compared with the retention times of other 10-, 11-, or 12- carbon molecules, depending on their structures.
See also
[edit]References
[edit]- ^ "undecane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 5 January 2012.
- ^ Yaws, Carl L. (1999). Chemical Properties Handbook. New York: McGraw-Hill. pp. 159–179. ISBN 0-07-073401-1.
- ^ Hölldobler B, Wilson EO (1990). The Ants. Harvard University Press. p. 287. ISBN 0-674-04075-9.
- ^ Stoermer, Martin (2023). "Undecane Isomers". Figshare. doi:10.6084/M9.FIGSHARE.24309724.
External links
[edit]- Undecane at Dr. Duke's Phytochemical and Ethnobotanical Databases