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Undirected biocatalytic amination of unactivated C(sp 3)−H bonds
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https://doi.org/10.1016/j.checat.2022.11.013Abstract
Selective catalytic functionalization of C(sp 3)-H bonds represents a powerful means to access valuable products from ubiquitous starting materials. In a recent JACS paper, Arnold and co-workers engineered P450 nitrene transferases to aminate unactivated C(sp 3)-H bonds with excellent site- and stereoselectivities.
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