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Search Results (769)

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17 pages, 2661 KiB  
Article
Debonding Detection of Thin-Walled Adhesive Structure by Electromagnetic Acoustic Resonance Technology
by Ne Liu, Shiqiang Shen, Ying Zhu, Ying Gao and Yongdong Pan
Materials 2024, 17(20), 5073; https://doi.org/10.3390/ma17205073 - 17 Oct 2024
Abstract
The detection of debonding defects in thin-walled adhesive structures, such as clad-iron/rubber layers on the leading edges of helicopter blades, presents significant challenges. This paper proposes the application of electromagnetic acoustic resonance technology (EMAR) to identify these defects in thin-walled adhesive structures. Through [...] Read more.
The detection of debonding defects in thin-walled adhesive structures, such as clad-iron/rubber layers on the leading edges of helicopter blades, presents significant challenges. This paper proposes the application of electromagnetic acoustic resonance technology (EMAR) to identify these defects in thin-walled adhesive structures. Through theoretical and simulation studies, the frequency spectrum of ultrasonic vibrations in thin-walled adhesive structures with various defects was analyzed. These studies verified the feasibility of applying EMAR to identify debonding defects. The identification of debonding defects was further examined, revealing that cling-type debonding defects could be effectively detected using EMAR by exciting shear waves with the minimum defect diameter at 5 mm. Additionally, the method allows for the quantitative analysis of these defects in the test sample. Due to the limited size of the energy exchange region in the transducer, the quantitative error becomes significant when identifying debonding defects smaller than this region. The EMAR identified debonding defects in clad-iron structures of rotor blades with a maximum error of approximately 15%, confirming its effectiveness for inspecting thin-walled adhesive structures. Full article
13 pages, 4051 KiB  
Article
Performance Evaluation of Pebble Concrete for Pavement: A Study on the Sucre Highway Project
by Zhuqing Feng, Jue Lu, Simin Liu, Jingliang Xia, Jing Wang, Faguang Leng and Xinxin Ma
Materials 2024, 17(20), 4994; https://doi.org/10.3390/ma17204994 - 12 Oct 2024
Viewed by 256
Abstract
Bolivia has abundant pebbles, while the supply of crushed stone is limited and unstable. Thus, the resource utilization of local pebble as a coarse aggregate and the guarantee of concrete durability are the key scientific issues in the Sucre Highway Project. In this [...] Read more.
Bolivia has abundant pebbles, while the supply of crushed stone is limited and unstable. Thus, the resource utilization of local pebble as a coarse aggregate and the guarantee of concrete durability are the key scientific issues in the Sucre Highway Project. In this paper, a comparative analysis was conducted of the performance of crushed stone concrete and pebble concrete. Additionally, the impact of fly ash on the water permeability resistance of concrete was investigated. The results indicate that the apparent density, bulk density, and void ratio of pebbles are lower than those of crushed stone, and the aggregate gradation of pebbles is dispersed. The type of aggregate is the primary factor influencing the splitting tensile strength of concrete, with the main failure modes of pebble concrete being slurry cracking, aggregate crushing, and interface debonding. While aggregate and fly ash have a minor effect on compressive strength, they significantly impact flexural tensile strength; however, all concretes meet the requirements for extra-heavy, very heavy, and heavy traffic load levels. In terms of impermeability, fly ash effectively mitigates the negative impact of aggregate type on the impermeability of concrete. These findings support the application of pebble concrete in the highway project. Full article
(This article belongs to the Special Issue Sustainable Pavement Materials and Their Performance Evaluation)
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21 pages, 18454 KiB  
Article
Image-Based Peridynamic Modeling-Based Micro-CT for Failure Simulation of Composites
by Zhuo Wang, Ling Zhang, Jiandong Zhong, Yichao Peng, Yi Ma and Fei Han
Materials 2024, 17(20), 4987; https://doi.org/10.3390/ma17204987 - 12 Oct 2024
Viewed by 425
Abstract
By utilizing computed tomography (CT) technology, we can gain a comprehensive understanding of the specific details within the material. When combined with computational mechanics, this approach allows us to predict the structural response through numerical simulation, thereby avoiding the high experimental costs. In [...] Read more.
By utilizing computed tomography (CT) technology, we can gain a comprehensive understanding of the specific details within the material. When combined with computational mechanics, this approach allows us to predict the structural response through numerical simulation, thereby avoiding the high experimental costs. In this study, the tensile cracking behavior of carbon–silicon carbide (C/SiC) composites is numerically simulated using the bond-based peridynamics model (BB-PD), which is based on geometric models derived from segmented images of three-dimensional (3D) CT data. To obtain results efficiently and accurately, we adopted a deep learning-based image recognition model to identify the kinds of material and then the pixel type that corresponds to the material point, which can be modeled by BB-PD for failure simulation. The numerical simulations of the composites indicate that the proposed image-based peridynamics (IB-PD) model can accurately reconstruct the actual composite microstructure. It can effectively simulate various fracture phenomena such as interfacial debonding, crack propagation affected by defects, and damage to the matrix. Full article
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12 pages, 2984 KiB  
Article
Response of a Blood Clot Adherent to Bone, Oral Mucosa and Hard Dental Tissues to a Uniaxial Tensile Test: An In Vitro Study
by Gaia Pellegrini, Roberto Fedele, Daniela Carmagnola, Claudia Dellavia, Giorgio Pagni, Dolaji Henin, Gianguido Cossellu, Sabrine Fessi and Giulio Rasperini
Medicina 2024, 60(10), 1673; https://doi.org/10.3390/medicina60101673 - 12 Oct 2024
Viewed by 317
Abstract
Background and Objectives: Periodontal therapy aims to arrest the progression of periodontal diseases and possibly to regenerate the periodontal apparatus. To shift healing from repair to regeneration, the blood clot that fills the periodontal defect and remains in contact with structures such [...] Read more.
Background and Objectives: Periodontal therapy aims to arrest the progression of periodontal diseases and possibly to regenerate the periodontal apparatus. To shift healing from repair to regeneration, the blood clot that fills the periodontal defect and remains in contact with structures such as tooth root, mucosa and bone needs to be stable, which is a reason why the treatment of non-containing periodontal bone defects, in which the clot may undergo displacement, is challenging. The gingival soft tissue, properly sutured, may act as a wall for blood clot stabilization. Knowledge on the response of the blood clot to stress and how it might vary according to the characteristics of the tissues it gets in contact with might be deepened. The aim of this study was to investigate in vitro, by means of a micro-loading device, the response of the complex formed by a blood clot and diverse tissues, simulating those involved in periodontal regeneration, to a displacing tensile test. Materials and Methods: Experimental samples made of two layers of either hard dental tissues, cancellous bone or oral mucosa, between which fresh blood was interposed, underwent a debonding experiment by means of a micro-loading device that measured their response to uniaxial tensile stress. Results: The peak of tensile stress and the overall work needed for the complete rupture of the clot’s fibrin filaments were significantly higher for hard dental tissues than for other tissues. However, mucosa sustained the highest maximal strain in terms of relative displacement between the plates of the micro-loading device to accomplish the complete rupture of the fibrin filaments compared to the other tissues, suggesting that the mucosa might act as a stable interface with the clot and be able to sustain tensile stresses. Conclusions: This in vitro study seems to support the use of mucosa to act as a wall for regenerative procedures of suprabony periodontal defects given its capability to form a stable interface with the clot. Full article
(This article belongs to the Section Dentistry and Oral Health)
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17 pages, 4231 KiB  
Article
Flexural Behavior of an RC Beam Externally Strengthened with a Steel- and CFRP-Based Method
by Yu Lin, Yang Wei, Zihan Gong, Wenping Xu and Kang Zhao
Appl. Sci. 2024, 14(20), 9281; https://doi.org/10.3390/app14209281 - 12 Oct 2024
Viewed by 437
Abstract
Reinforced concrete beam bridges are usually retrofitted by a steel plate or FRP. However, these two methods tend to result in disadvantages, e.g., construction complexity and debonding failure, owing to the corresponding material properties. In this study, a steel- and CFRP-based method is [...] Read more.
Reinforced concrete beam bridges are usually retrofitted by a steel plate or FRP. However, these two methods tend to result in disadvantages, e.g., construction complexity and debonding failure, owing to the corresponding material properties. In this study, a steel- and CFRP-based method is proposed to achieve the merits of typical retrofitting methods by combining a CFRP plate, a steel plate, and angle steel. To investigate the effect of the cooperative strengthening, six full-scale beam specimens were designed and are evaluated through a monotonic four-point bending test. The failure mode, load–deflection relationship, critical parameters, and crack development are systematically and sequentially analyzed. Finally, a predicting method is proposed to calculate the flexural capacity. The retrofitted beam is characterized by an acceptable load-bearing capacity and deformation capacity. With continuous retrofitting, the crack load and ultimate load can be improved up to 84.9% and 4.41 times, respectively. The steel plate and angle steel function in both the load bearing and the anchorage to the CFRP plate contributes more to the ultimate bearing capacity after the steel components yield. Finally, a calculating model is shown to accurately predict the ultimate bearing capacity after retrofitting, with an average error of 4.03%. Full article
(This article belongs to the Section Civil Engineering)
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15 pages, 6728 KiB  
Article
Flexural Analysis of Additively Manufactured Continuous Fiber-Reinforced Honeycomb Sandwich Structures
by Rafael Guerra Silva, Esteban Gonzalez, Andres Inostroza and Gustavo Morales Pavez
J. Manuf. Mater. Process. 2024, 8(5), 226; https://doi.org/10.3390/jmmp8050226 - 10 Oct 2024
Viewed by 530
Abstract
This study explores the flexural behavior of continuous fiber-reinforced composite sandwich structures built entirely using material extrusion additive manufacturing. The continuous fiber additive manufacturing system used in this study works sequentially, thus enabling the addition of fiber reinforcement just in the face sheets, [...] Read more.
This study explores the flexural behavior of continuous fiber-reinforced composite sandwich structures built entirely using material extrusion additive manufacturing. The continuous fiber additive manufacturing system used in this study works sequentially, thus enabling the addition of fiber reinforcement just in the face sheets, where it is most effective. Three-point bending tests were carried out on sandwich panel specimens built using thermoplastic reinforced with continuous glass fiber to quantify the effect of fiber reinforcement and infill density in the flexural properties and failure mode. Sandwich structures containing continuous fiber reinforcement had higher flexural strength and rigidity than unreinforced sandwiches. On the other hand, an increase in the lattice core density did not improve the flexural strength and rigidity. The elastic modulus of fiber-reinforced 3D-printed sandwich panels exceeded the predictions of the analytical models; the equivalent homogeneous model had the best performance, with a 15% relative error. However, analytical models could not correctly predict the failure mode: wrinkle failure occurs at 75% and 30% of the critical load in fiber-reinforced sandwiches with low- and high-density cores, respectively. Furthermore, no model is currently available to predict interlayer debonding between the matrix and the thermoplastic coating of fiber layers. Divergences between analytical models and experimental results could be attributed to the simplifications in the models that do not consider defects inherent to additive manufacturing, such as air gaps and poor interlaminar bonding. Full article
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20 pages, 7356 KiB  
Article
Structural Behaviour and Mechanical Characteristics of BlueDeck Profiled Steel Sheeting for Use in Composite Flooring Systems
by Harry Far, Shami Nejadi and Suleiman A. Al-Hunaity
Buildings 2024, 14(10), 3204; https://doi.org/10.3390/buildings14103204 - 9 Oct 2024
Viewed by 530
Abstract
The BlueDeck profiled steel sheeting system offers an innovative composite flooring solution, integrating high-strength steel sheets with reinforced concrete to form a unified structure. This study aimed to evaluate the development of full composite action, the ultimate bearing capacity, and the flexural stiffness [...] Read more.
The BlueDeck profiled steel sheeting system offers an innovative composite flooring solution, integrating high-strength steel sheets with reinforced concrete to form a unified structure. This study aimed to evaluate the development of full composite action, the ultimate bearing capacity, and the flexural stiffness of the system. A comprehensive experimental programme involving 18 four-point bending tests and 6 shear tests was conducted to quantify the mechanical interaction between the steel deck and concrete slab. This study specifically examined bending capacity and vertical deflection, comparing the results with predictions from AS/NZS 2327. It was found that the system consistently achieved full composite action, with composite specimens demonstrating higher flexural stiffness and load-bearing capacity as the concrete depth increased. For example, specimens with 200 mm slab depths exhibited a 60% improvement in ultimate capacity compared to those with 150 mm slabs, while those with 175 mm depths saw a 27% increase. Additionally, the BlueDeck system showed an 81% improvement in de-bonding resistance in thicker slabs. The experimental results exceeded the bending moment and deflection limits prescribed by AS/NZS 2327, confirming that the system is structurally sound for use in buildings. This study provides quantitative evidence supporting the system’s compliance with Australian standards, highlighting its potential for improving construction efficiency through reduced material use, while maintaining structural integrity under imposed loads. Full article
(This article belongs to the Section Building Structures)
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17 pages, 3978 KiB  
Article
Study on Flexural Performance of Reinforced Concrete Beams Strengthened with FRP Grid–PCM Composite Reinforcement
by Zhimei Zhang and Haixue Qin
Appl. Sci. 2024, 14(19), 9013; https://doi.org/10.3390/app14199013 - 6 Oct 2024
Viewed by 531
Abstract
To study the flexural performance of fiber-reinforced polymer (FRP) grid–polymer cement mortar (PCM)-composite-strengthened RC beams, the finite element numerical simulation of FRP grid–PCM composite RC beams is carried out using ABAQUS to analyze the effects of the amount of FRP grid reinforcement, the [...] Read more.
To study the flexural performance of fiber-reinforced polymer (FRP) grid–polymer cement mortar (PCM)-composite-strengthened RC beams, the finite element numerical simulation of FRP grid–PCM composite RC beams is carried out using ABAQUS to analyze the effects of the amount of FRP grid reinforcement, the type of FRP grid material, and the geometry of FRP grid on the flexural performance of reinforced concrete beams and to establish the flexural capacity calculation formula of FRP grid–PCM-reinforced RC beams in case of debonding failure, based on analysis of the influencing factors. The results show that increasing the reinforcement of the FRP grid and increasing the stiffness of the FRP grid can improve the flexural bearing capacity of RC beams, and the change of FRP grid geometry has little effect on the flexural bearing capacity of RC beams. The established formula for calculating the flexural bearing capacity of FRP grid-reinforced concrete beams can better predict the flexural capacity of reinforced concrete beams under peeling failure. Full article
(This article belongs to the Special Issue Intelligence and Automation in Construction, 2nd Edition)
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14 pages, 4968 KiB  
Article
A Quantitative Study of Axial Performance of Rockbolts with an Elastic–Debonding Model
by Jianhang Chen, Xiaofan Zeng, Banquan Zeng, Junming Ma, Shimo Sun and Saisai Wu
Appl. Sci. 2024, 14(19), 8966; https://doi.org/10.3390/app14198966 - 5 Oct 2024
Viewed by 385
Abstract
Full-length anchorage rockbolts are widely used in roadway reinforcement and rock controlling in underground mining. This article proposes using an elastic–debonding (ED) model to analyse the axial performance of rockbolts. The advantage of this ED model was that the full force–deformation curve of [...] Read more.
Full-length anchorage rockbolts are widely used in roadway reinforcement and rock controlling in underground mining. This article proposes using an elastic–debonding (ED) model to analyse the axial performance of rockbolts. The advantage of this ED model was that the full force–deformation curve of rockbolts comprised only three phases, which was relatively simpler to calculate. Its effectiveness was compared with experiment tests. Based on the ED model, a series of parameter studies was conducted. Results showed that for cross-section area of rock, there was a critical range. Once the cross-section area of rock was beyond that critical range, external rock had a mild impact on the axial performance of rockbolts. Rockbolt diameter significantly affected the axial performance of rockbolts. When rock diameter increased, the peak force of rockbolts increased linearly, while deformation at the peak force decreased non-linearly. The corresponding calculation equation between the peak force, deformation at the peak force, and rockbolt diameter was obtained. Borehole diameter had a mild impact on the axial performance of rockbolts. Increasing rockbolt length benefits improving the peak force of rockbolts. Rockbolt modulus of elasticity had a more apparent impact on the deformation at peak force. Mechanical properties of the bolt/grout (b/g) face affected the axial performance of rockbolts. Increasing the b/g face strength improved the peak force of rockbolts. Slippage at the ultimate load had a more apparent impact on the turning point between the elastic phase and the elastic–softening phase. Full article
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20 pages, 7405 KiB  
Article
Stress Analysis of Glass Fiber-Reinforced Polymer Lap Joints with Modified Adhesives at Various Temperatures
by Hasan Caglar, Sridhar Idapalapati, Mohit Sharma and Chian Kerm Sin
J. Compos. Sci. 2024, 8(10), 406; https://doi.org/10.3390/jcs8100406 - 4 Oct 2024
Viewed by 507
Abstract
This study examines stress distributions in adhesive joints under various loading and temperature conditions. Finite element analysis (FEA) was employed to compute the peel and shear stresses at the adhesive interface and bondline mid-section. Dependency analysis shows that mid-section peel stress significantly impacts [...] Read more.
This study examines stress distributions in adhesive joints under various loading and temperature conditions. Finite element analysis (FEA) was employed to compute the peel and shear stresses at the adhesive interface and bondline mid-section. Dependency analysis shows that mid-section peel stress significantly impacts the experimental shear strength of SLJs more than shear stress. This insight highlights the need to carefully analyze peel stress and bending moment factors. The analytical solutions proposed by Goland and Reissner were analyzed with modifications by Hart-Smith and Zhao. Hart-Smith’s approach performed more effectively, especially when the adhesive layer thickness (ta) was 0.5 mm and the overlap length to thickness ratio (c/ta) was ≥20. FEA revealed stress distributions at the adhesive/adherend interface and bondline mid-section. DP490 adhesive joints exhibited lower stresses than EA9696. Temperature variations significantly affected joint behavior, particularly above the adhesive’s glass transition temperature (Tg). Both EA9696 and DP490 adhesive joints displayed distinct responses to stress and temperature changes. The parabolic and biquadratic solutions for functionally graded adhesive (FGA) joints were compared. The biquadratic solution consistently yielded higher shear and peel stress values, with an increase ranging from 15% to 71% compared to the parabolic solution at various temperatures because of the larger gradient of the Young’s modulus distribution near the overlap ends. The ratio of peak peel stress to peak shear stress suggests that selecting an adhesive with a superior peel strength or primarily reducing the peak peel stress by functionally grading is advisable, particularly if the adhesive is brittle. The comparison of stress distributions emphasizes the importance of selecting adhesives based on stress type, temperature, and solution methods in optimizing adhesive bonding applications. These findings provide valuable insights for thermomechanical applications where thermal stimuli may be used for controlled debonding. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, 3rd Edition)
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20 pages, 7079 KiB  
Article
Cement-Formation Debonding Due to Temperature Variation in Geothermal Wells: An Intensive Numerical Simulation Assessment
by Ionut Lambrescu, Khizar Abid and Catalin Teodoriu
Energies 2024, 17(19), 4953; https://doi.org/10.3390/en17194953 - 3 Oct 2024
Viewed by 700
Abstract
Geothermal wells are subjected to higher loads compared to conventional oil and gas wells due to the thermal cycles that occur during both production and non-production phases. These temperature variations can affect the cohesion of the cement within the formation and casing, creating [...] Read more.
Geothermal wells are subjected to higher loads compared to conventional oil and gas wells due to the thermal cycles that occur during both production and non-production phases. These temperature variations can affect the cohesion of the cement within the formation and casing, creating micro-annuli channels that can ultimately compromise the integrity of the well. Therefore, this study employs an intensive finite element methodology to analyze the debonding criteria of casing–cement systems in geothermal wells by examining over 36 independent models. The wellbore cooling and heating processes were simulated using three cohesive zone models (CZM): Type I (tensile), Type II (shear), and mixed (Type I and II simultaneously). The analysis revealed that Type I debonding occurs first during cooling at a temperature of around 10 °C, while Type II is the primary failure mode during heating. Evaluations of interfacial bonding shear strength (IBSS) values indicated that the debonding of the cement would even occur at high IBSS values (3 and 4 MPa) at a differential temperature of 300 °C, while the other IBSS of 1 MPa withstands only 60 °C. However, achieving an IBSS of 4 MPa with current technology is highly unlikely. Therefore, geothermal well operation and construction must be modified to keep the differential temperature below the critical temperature at which the debonding of the cement initiates. The study also found that debonding during cooling happens at lower differential temperatures due to generally lower values for interfacial bonding tensile strength (IBTS), typically less than 1 MPa. The novelty of the study is that it provides new insights into how specific temperatures trigger different types of debonding, highlights that high IBSS values may not prevent debonding at high differential temperatures, and recommends operational adjustments to maintain temperatures below critical levels to enhance cement integrity. Additionally, this study reveals that debonding during cooling occurs at a lower differential temperature change due to the reduced value of the interfacial bonding tensile strength (IBTS). Full article
(This article belongs to the Section H: Geo-Energy)
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13 pages, 2704 KiB  
Article
Synthesis and Characterization of Rebondable Polyurethane Adhesives Relying on Thermo-Activated Transcarbamoylation
by Daniel Bautista-Anguís, Lisbeth Reiner, Florian Röper, Sebastian Maar, Markus Wolfahrt, Archim Wolfberger and Sandra Schlögl
Polymers 2024, 16(19), 2799; https://doi.org/10.3390/polym16192799 - 3 Oct 2024
Viewed by 574
Abstract
Dynamic polymer networks combine the noteworthy (thermo)mechanical features of thermosets with the processability of thermoplastics. They rely on externally triggered bond exchange reactions, which induce topological rearrangements and, at a sufficiently high rate, a macroscopic reflow of the polymer network. Due to this [...] Read more.
Dynamic polymer networks combine the noteworthy (thermo)mechanical features of thermosets with the processability of thermoplastics. They rely on externally triggered bond exchange reactions, which induce topological rearrangements and, at a sufficiently high rate, a macroscopic reflow of the polymer network. Due to this controlled change in viscosity, dynamic polymers are repairable, malleable, and reprocessable. Herein, several dynamic polyurethane networks were synthetized as model compounds, which were able to undergo thermo-activated transcarbamoylation for the use in rebondable adhesives. Ethylenediamine-N,N,N′,N′-tetra-2-propanol (EDTP) was applied as a transcarbamoylation catalyst, which participates in the curing reaction across its four -OH groups and thus, is covalently attached within the polyurethane network. Both bond exchange rate and (thermo)mechanical properties of the dynamic networks were readily adjusted by the crosslink density and availability of -OH groups. In a last step, the most promising model compound was optimized to prepare an adhesive formulation more suitable for a real case application. Single-lap shear tests were carried out to evaluate the bond strength of this final formulation in adhesively bonded carbon fiber reinforced polymers (CFRP). Exploiting the dynamic nature of the adhesive layer, the debonded CFRP test specimens were rebonded at elevated temperature. The results clearly show that thermally triggered rebonding was feasible by recovering up to 79% of the original bond strength. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
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13 pages, 4296 KiB  
Article
Enhancing the Mechanical Properties of Injectable Nanocomposite Hydrogels by Adding Boronic Acid/Boronate Ester Dynamic Bonds at the Nanoparticle–Polymer Interface
by Jesús Sánchez, Jose Ulloa, Yessenia Oyarzún, Matías Ceballos, Carla Ruiz, Bruno Boury and Bruno F. Urbano
Gels 2024, 10(10), 638; https://doi.org/10.3390/gels10100638 - 2 Oct 2024
Viewed by 472
Abstract
Incorporating nanoparticles into injectable hydrogels is a well-known technique for improving the mechanical properties of these materials. However, significant differences in the mechanical properties of the polymer matrix and the nanoparticles can result in localized stress concentrations at the polymer–nanoparticle interface. This situation [...] Read more.
Incorporating nanoparticles into injectable hydrogels is a well-known technique for improving the mechanical properties of these materials. However, significant differences in the mechanical properties of the polymer matrix and the nanoparticles can result in localized stress concentrations at the polymer–nanoparticle interface. This situation can lead to problems such as particle–matrix debonding, void formation, and material failure. This work introduces boronic acid/boronate ester dynamic covalent bonds (DCBs) as energy dissipation sites to mitigate stress concentrations at the polymer–nanoparticle interface. Once boronic acid groups were immobilized on the surface of SiO2 nanoparticles (SiO2-BA) and incorporated into an alginate matrix, the nanocomposite hydrogels exhibited enhanced viscoelastic properties. Compared to unmodified SiO2 nanoparticles, introducing SiO2 nanoparticles with boronic acid on their surface improved the structural integrity and stability of the hydrogel. In addition, nanoparticle-reinforced hydrogels showed increased stiffness and deformation resistance compared to controls. These properties were dependent on nanoparticle concentration. Injectability tests showed shear-thinning behavior for the modified hydrogels with injection force within clinically acceptable ranges and superior recovery. Full article
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26 pages, 29595 KiB  
Article
Induction Heating of Laminated Composite Structures with Magnetically Responsive Nanocomposite Interlayers for Debonding-on-Demand Applications
by Eleni Gkartzou, Konstantinos Zafeiris, Christos Tsirogiannis, Alberto Pedreira, Adrián Rodríguez, Pablo Romero-Rodriguez, Giorgos P. Gakis, Tatjana Kosanovic-Milickovic, Apostolos Kyritsis and Costas A. Charitidis
Polymers 2024, 16(19), 2760; https://doi.org/10.3390/polym16192760 - 30 Sep 2024
Viewed by 587
Abstract
In the present study, the feasibility to achieve localized induction heating and debonding of multi-material composite structures is assessed in testing coupons prepared by Automated Fiber Placement (AFP) and extrusion-based additive manufacturing (AM) technologies. Nano-compounds of Polyether-ketone-ketone (PEKK) with iron oxide nanoparticles acting [...] Read more.
In the present study, the feasibility to achieve localized induction heating and debonding of multi-material composite structures is assessed in testing coupons prepared by Automated Fiber Placement (AFP) and extrusion-based additive manufacturing (AM) technologies. Nano-compounds of Polyether-ketone-ketone (PEKK) with iron oxide nanoparticles acting as electromagnetic susceptors have been processed in a parallel co-rotating twin-screw extruder to produce filament feedstock for extrusion-based AM. The integration of nanocomposite interlayers as discrete debonding zones (DZ) by AFP-AM manufacturing has been investigated for two types of sandwich-structured laminate composites, i.e., laminate-DZ-laminate panels (Type I) and laminate-DZ-AM gyroid structures (Type II). Specimens were exposed to an alternating magnetic field generated by a radio frequency generator and a flat spiral copper induction coil, and induction heating parameters (frequency, power, heating time, sample standoff distance from coil) have been investigated in correlation with real-time thermal imaging to define the debonding process window without compromising laminate quality. For the optimized process parameters, i.e., 2–3 kW generator power and 20–25 mm standoff distance, corresponding to magnetic field intensities in the range of 3–5 kA m−1, specimens were effectively heated above PEKK melting temperature, exhibiting high heating rates within the range of 5.3–9.4 °C/s (Type I) and 8.0–17.5 °C/s (Type II). The results demonstrated that localized induction heating successfully facilitated debonding, leading to full unzipping of the debonding zones in both laminate structures. Further insight on PEKK nanocomposites debonding performance was provided by thermal, morphological characterization and non-destructive inspection via X-ray micro-computed tomography at different processing stages. The developed framework aims to contribute to the development of rapid, on-demand joining, repair and disassembly technologies for thermoplastic composites, towards more efficient maintenance, repair and overhaul operations in the aviation sector and beyond. Full article
(This article belongs to the Special Issue Polymeric Materials and Their Application in 3D Printing, 2nd Edition)
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13 pages, 3511 KiB  
Article
Enhancing Shear Bond Strength in Lithium Silicate Glass Ceramics: Surface Treatment Optimization for Reseating Protocols
by Allison Torbiak, Muna Bebsh, Asmaa Haimeur, Ana Carla Fernandes, Cristina Fiuza and Rodrigo França
Crystals 2024, 14(10), 856; https://doi.org/10.3390/cryst14100856 - 29 Sep 2024
Viewed by 481
Abstract
The rapid evolution of lithium silicate-based glass ceramics in the field of dental ceramics has led to the availability of different compositions in the market. This in vitro study was conducted to assess an effective protocol for recementing de-bonded lithium silicate-based glass ceramics [...] Read more.
The rapid evolution of lithium silicate-based glass ceramics in the field of dental ceramics has led to the availability of different compositions in the market. This in vitro study was conducted to assess an effective protocol for recementing de-bonded lithium silicate-based glass ceramics by evaluating the shear bond strength of three reseating methods. The study included IPS e.max® CADきゃど, Vita Suprinity®, Celtra Duo®, and n!ce as lithium-based glass ceramics. The samples underwent a series of preparation steps, including embedding in acrylic resin, hand polishing, etching with 5% hydrofluoric acid, and application of universal primer and adhesive as per manufacturer instructions. Subsequently, adhesive resin cement was applied to the ceramic tablets, and shear bond strength was assessed using a standardized method. The findings revealed that no single method demonstrated significantly superior results compared to the others. However, it was observed that etching with 5% hydrofluoric acid for 20 s yielded favorable outcomes in terms of time efficiency and standardized results. Additionally, it was noted that although sandblasting increased surface area, it did not enhance bond strength due to unfavorable surface disturbance. In conclusion, the study suggests that etching with 5% hydrofluoric acid for 20 s is a favorable protocol for reseating de-bonded lithium disilicate-based glass ceramics, offering both time efficiency and consistent results for clinicians. Full article
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