二 氯化锗
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IUPAC Germanium dichloride | |
Dichlorogermanylidene | |
别名 | 氯化锗(II) 氯化亚锗 |
识别 | |
CAS |
10060-11-4 ? |
PubChem | 6327122 |
ChemSpider | 4885679 |
SMILES |
|
InChI |
|
InChIKey | QHGIKMVOLGCZIP-UHFFFAOYSA-N |
EINECS | 233-192-1 |
GeCl2 | |
143.546 g·mol⁻¹ | |
制 备
编辑
GeCl2
- GeCl4 + Ge → 2GeCl2
它也
- GeHCl3 → GeCl2 + HCl
- GeCl
4 + H
2 → GeCl
2 + 2HCl
反 应
编辑
GeCl2
- GeCl2(aq) + 2H2O(l) ⇌ Ge(OH)2(s) + 2HCl(aq)
- Ge(OH)2 → GeO + H2O
- Ge2+(aq) + 2OH−(aq) = Ge(OH)2(s)
锗的氧化
GeCl2分子
编辑
GeCl2
参考 资料
编辑
- ^ 1.0 1.1 1.2 1.3 Greenwood, N. N.; Earnshaw, A. Chemistry of the Elements 2nd. Oxford:Butterworth-Heinemann. 1997. ISBN 0-7506-3365-4.
- ^ Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
- ^ Kociok-Köhn, G.; Winter, J. G.; Filippou, A. C. Trimethylphosphonium trichlorogermanate(II). Acta Crystallogr. C. 1999, 55 (3): 351–353. doi:10.1107/S010827019801169X .
- ^ Tsuchiya, Masaki J.; Honjou, Hiroaki; Tanaka, Keiichi; Tanaka, Takehiko. Millimeter-wave spectrum of germanium dichloride GeCl2. Equilibrium structure and anharmonic force field. Journal of Molecular Structure. 1995,. 352–353: 407–415. Bibcode:1995JMoSt.352..407T. doi:10.1016/0022-2860(95)08830-O.
- ^ Egorov, M.P.; Gaspar, P. Germanium: Organometallic chemistry. Encyclopedia of Inorganic chemistry. John Wiley & Sons. 1994. ISBN 0-471-93620-0.