乙おつ酰丙酮钕

乙おつ酰丙酮钕
英文えいぶん名めい	Neodymium acetylacetonate
识别
CAS号ごう	14589-38-9
性せい质
化学かがく式しき	C15H21NdO6
摩ま尔质量りょう	441.57 g·mol−1
外そと观	粉こな色しょく粉末ふんまつ
熔点	150 °C（423 K）
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

乙おつ酰丙酮钕是ぜ一いち种配はい位い化合かごう物ぶつ，化学かがく式しき为Nd(C₅H₇O₂)₃，或ある简写为Nd(acac)₃，它的不ふ稳定常数じょうすう（logY_n）分ぶん别为2.89、4.15和わ5.26（对应n=1, 2, 3）。^[2]它可由よし三烷氧基钕和乙おつ酰丙酮反はん应制得え，^[3]或ある通つう过金属きんぞく钕在ざい乙おつ酰丙酮中电解得え到いた。^[4]它的二水合物和羰基铼配合物Re(CO)₃X(4,4'-bipy)（X=Cl, Br）反はん应，可か以得到いたRe(CO)₃X(4,4'-bipy)Nd(acac)₃。^[5]

参考さんこう文献ぶんけん

^ ^1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始げんし内容ないよう存そん档于2021-10-17）.
^ N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始げんし内容ないよう存そん档于2018-06-24）（英えい语）.
^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄にわか文ぶん）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
^ Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.
^ Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄にわか文ぶん）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

[Pierson-1] 1.0 ^1.1 Pierson, H.O. Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. 1999: 92 [2021-09-16]. ISBN 978-0-8155-1743-6. （原始げんし内容ないよう存そん档于2021-10-17）.

[2] N.K. Dutt, P. Banyopadhyay. Chemistry of the lanthanons—XIII. Journal of Inorganic and Nuclear Chemistry. 1964-05, 26 (5): 729–736 [2021-09-20]. doi:10.1016/0022-1902(64)80316-X. （原始げんし内容ないよう存そん档于2018-06-24）（英えい语）.

[3] Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates（俄にわか文ぶん）. Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.

[4] Panyushkin, V. T.; Frolov, V. Yu.; Zelenov, V. I. Electrochemical synthesis of rare-earth metal acetylacetonates. Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii), 2001. 71 (8): 1318.

[5] Shapoval, A. N.; Bobukhov, D. V.; Rusakova, N. V.; Shtemenko, A. V.; Snurnikova, O. V.; Korovin, Yu. V. Synthesis and spectral-luminescent properties of mono- (Re⁺) and heteronuclear (Re⁺-Ln³⁺) tricarbonyl-halo complexes（俄にわか文ぶん）. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2007. 73 (9-10): 34-36. ISSN 0041-6045.

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