氟化锰

氟化锰
	IUPAC名めい; Manganese(II) fluoride
别名	二に氟化锰; 氟化亚锰; C.I. 77738
识别
CAS号ごう	7782-64-1
PubChem	24528
ChemSpider	22935
SMILES	F[Mn]F;
InChI	1/2FH.Mn/h2*1H;/q;;+2/p-2;
InChIKey	CTNMMTCXUUFYAP-NUQVWONBAJ
RTECS	OP0875000
性せい质
化学かがく式しき	MnF2
摩ま尔质量りょう	92.934855 g·mol⁻¹
外そと观	淡あわ粉こな红色晶あきら体からだ
密度みつど	3.922 g/cm3（25 °C）
熔点	856 °C
沸点ふってん	1820 °C
溶解ようかい性せい（水みず）	微ほろ溶于水すい
结构
晶あきら体からだ结构	P42/mnm（No.136）等ひとし
危险性せい
警示术语	R：R20/21/22、R36/37/38
安全あんぜん术语	S：S26、S37/39
欧おう盟めい编号	未み列れつ出で
	GHS危险性せい符号ふごう;
GHS提示ていじ词	警告けいこく
H-术语	H302, H312, H315, H319, H332, H335
P-术语	P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P321, P322, P330
闪点	不ふ可燃かねん
相あい关物质
其他阴离子こ	二に氯化锰; 二に溴化锰; 二に碘化锰
其他阳离子こ	六ろく氟化锝; 七なな氟化铼; 三さん氟化锰
相あい关化学かがく品ひん	一いち氧化锰
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

氟化锰是ぜ一いち种无机つくえ化合かごう物ぶつ，化学かがく式しき为MnF₂。它是一种淡粉红色固体，其颜色しょく源げん自じ于二价锰离子的特征色。它可用よう于特种玻璃はり和わ激げき光こう器き的まと制せい造づくり。^[3]

制せい备与结构

氟化锰可由ゆかり碳酸锰和わ氢氟酸さん反はん应制得とく：^[4]

MnCO₃ + 2 HF → MnF₂ + CO₂↑ + H₂O

也可由ゆかり氯化锰和かず过量的てき氟化铵反はん应，得とく到いたNH₄MnF₃，它在二に氧化碳中ちゅう加か热至290~300 °C得え到いた氟化锰。^[5]它也能のう通どおり过四よん氧化三さん锰（或ある草くさ酸さん锰）与あずか氟化铵加か热反应制得とく。^[6]

氟化锰存在そんざい多た种晶相しょう，P4₂/mnm(金きむ红石型がた)和わP42m是ぜ已やめ知的ちてき，^[7]金きむ红石型がた的てき氟化锰在高だか压会转变为αあるふぁ-PbO₂相そう。^[8]

反はん应

氟化锰和M₂MnF₆（M=K, Rb, Cs）在ざい真空しんくう中ちゅう加か热（或ある氮气环境下か加か压，M=NH₄）反はん应，可か以得到いた相あい应的MMnF₄。^[9]它可以被氟气氧化至いたり四よん氟化锰；^[10]而在氟化氢中なか的てき反はん应会生成せいせい三さん氟化锰，氟化氢中生成せいせい四氟化锰还需紫外光的照射。^[11]它和三さん氟化锰反はん应，还能得え到いたMn₂F₅和わMn₃F₈。^[12]氟化锰和过量二に氟化氙加か热反应，可か以得到いたXeF₂·MnF₄，反はん应中Mn²⁺被ひ氧化至いたりMn⁴⁺；^[13]KrF₂·MnF₄则需在ざい低温ていおん氟化氢中なか由ゆかり氟化锰和二に氟化氪反はん应得到いた，室温しつおん时，它会分解ぶんかい为四よん氟化锰、二に氟化氪、氪和わ氟气。^[14]

它在潮しお湿しめ的てき氮气中ちゅう加か热至500 °C发生水みず解かい，生成せいせい一いち氧化锰，^[15]在ざい潮しお湿しめ空むなし气中加か热除了りょう水すい解かい外がい还会发生氧化反はん应；它和硫蒸ふけ气的反はん应发生せい在ざい氟化锰的表面ひょうめん。^[16]

参考さんこう文献ぶんけん

^ Griffel, Maurice; Stout, J. W. Preparation of Single Crystals of Manganous Fluoride. The Crystal Structure from X-Ray Diffraction. The Melting Point and Density. Journal of the American Chemical Society. October 1950, 72 (10): 4351–4353 [2022-07-13]. ISSN 0002-7863. doi:10.1021/ja01166a004. eISSN 1520-5126. （原始げんし内容ないよう存そん档于2022-07-18）.
^ 339288 Manganese(II) fluoride 98%. Sigma-Aldrich. [2008-06-18].
^ Ayres, D. C.; Hellier, Desmond. Dictionary of Environmentally Important Chemicals. CRC Press. 1997: 195 [2008-06-18]. ISBN 0-7514-0256-7.
^ Gmelin Handbook of Inorganic Chemistry. Springer-Verlag. 1977: 5 [2022-07-13]. ISBN 978-0-387-93343-6. （原始げんし内容ないよう存そん档于2022-07-17）（德とく语）.
^ Nuka, P. Zur Kenntnis der Fluoride des Mangans und Cadmiums. Zeitschrift für anorganische und allgemeine Chemie. 8 April 1929, 180 (1): 235–240 [2022-07-13]. ISSN 0863-1786. doi:10.1002/zaac.19291800125. eISSN 1521-3749. （原始げんし内容ないよう存そん档于2022-07-16）（德とく语）.
^ Pourroy, G.; Poix, P. New synthesis routes for difluorides MF₂ (M = Fe, Mn, Zn and Ni). Journal of Fluorine Chemistry. February 1989, 42 (2): 257–263 [2022-07-13]. ISSN 0022-1139. doi:10.1016/S0022-1139(00)82754-2. （原始げんし内容ないよう存そん档于2022-07-16）.
^ Lee, Jeong-Hyeon; Cho, K. K.; Lee, Jeon Ryang; Park, Jae Cheol; Jang, Hansaem; Cho, Beong Ki; Kim, Tae-Won. Manganese Fluoride Nanoparticles Synthesized by Microwave Irradiation Using Ionic Liquid–Ethylene Glycol Mixtures: Room-Temperature Photoluminescence, Crystalline Phase, and Morphology. Crystal Growth & Design. 28 January 2021, 21 (3): 1406–1412 [2022-07-13]. ISSN 1528-7483. doi:10.1021/acs.cgd.0c01522. eISSN 1528-7505. （原始げんし内容ないよう存そん档于2022-07-16）.
^ Vereshchagin, L. F.; Kabalkina, S. S.; Kotilevets, A. A. Phase transition in MnF₂ at high pressure. Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki. 1965, 49 (6): 1728-1732. ISSN 0044-4510 （俄にわか语）. CODEN ZETFA7.
^ Massa, W. Zur darstellung und strukturchemie der alkali-tetrafluoromanganate (III): CsMnF₄ und NH₄MnF₄. Inorganic and Nuclear Chemistry Letters. January 1977, 13 (5–6): 253–258 [2022-07-13]. ISSN 0020-1650. doi:10.1016/0020-1650(77)80103-7. （原始げんし内容ないよう存そん档于2018-06-29）（德とく语）.
^ Rakov, E. G.; Khaustov, S. V.; Ostropikov, V. V. Synthesis of manganese tetrafluoride at atmospheric pressure. Zhurnal Neorganicheskoi Khimii. 1998, 43 (4): 533–537. ISSN 0044-457X （俄にわか语）. CODEN ZNOKAQ.
^ Mazej, Z. Room temperature syntheses of MnF₃, MnF₄ and hexafluoromanganete(IV) salts of alkali cations. Journal of Fluorine Chemistry. March 2002, 114 (1): 75–80. ISSN 0022-1139. doi:10.1016/S0022-1139(01)00566-8.
^ Bandemehr, Jascha; Zimmerhofer, Fabian; Ivlev, Sergei I.; Pietzonka, Clemens; Eklund, Kim; Karttunen, Antti J.; Huppertz, Hubert; Kraus, Florian. Syntheses and Characterization of the Mixed-Valent Manganese(II/III) Fluorides Mn₂F₅ and Mn₃F₈. Inorganic Chemistry. 25 August 2021, 60 (17): 12651–12663 [2022-07-13]. ISSN 0020-1669. PMID 34431300. doi:10.1021/acs.inorgchem.1c01833. eISSN 1520-510X. （原始げんし内容ないよう存そん档于2022-07-13）.
^ Zemva, B.; Zupan, J.; Slivnik, Joze. Xenon fluoride-manganese fluoride reaction. Inst. Jozef Stefan, IJS Rep. 1970, (R585): 1-4. CODEN NJSRA9.
^ Lutar, Karel; Jesih, Adolf; Žemva, Boris. KrF₂/MnF₄ adducts from KrF₂/MnF₂ interaction In HF As a route to high purity MnF₄. Polyhedron. January 1988, 7 (13): 1217–1219 [2022-07-13]. ISSN 0277-5387. doi:10.1016/S0277-5387(00)81212-7. （原始げんし内容ないよう存そん档于2022-07-13）.
^ Baratali, Torabali; Abedini, Mansour. The hydrolysis of manganous fluoride. Journal of Inorganic and Nuclear Chemistry. January 1976, 38 (3): 604 [2022-07-13]. ISSN 0022-1902. doi:10.1016/0022-1902(76)80319-3. （原始げんし内容ないよう存そん档于2022-07-13）.
^ Ippolitov, E. G.; Tripol'skaya, T. A.; Zhigarnovskii, B. M. Study of 3d transition element fluorides. Zhurnal Neorganicheskoi Khimii. 1979, 24 (2): 539–541. ISSN 0044-457X （俄にわか语）. CODEN ZNOKAQ.

拓つぶせ展てん阅读

XIE, M; PENG, X; FU, X; ZHANG, J; LI, G; YU, X. Synthesis of Yb³⁺/Er³⁺ co-doped MnF₂ nanocrystals with bright red up-converted fluorescence. Scripta Materialia. February 2009, 60 (3): 190–193. ISSN 1359-6462. doi:10.1016/j.scriptamat.2008.10.010.
Baskurt, Mehmet; Nair, Rahul R.; Peeters, Francois M.; Sahin, Hasan. Ultra-thin structures of manganese fluorides: conversion from manganese dichalcogenides by fluorination. Physical Chemistry Chemical Physics. 2021, 23 (17): 10218–10224. ISSN 1463-9076. PMID 33881066. doi:10.1039/d1cp00293g. eISSN 1463-9084.

[1] Griffel, Maurice; Stout, J. W. Preparation of Single Crystals of Manganous Fluoride. The Crystal Structure from X-Ray Diffraction. The Melting Point and Density. Journal of the American Chemical Society. October 1950, 72 (10): 4351–4353 [2022-07-13]. ISSN 0002-7863. doi:10.1021/ja01166a004. eISSN 1520-5126. （原始げんし内容ないよう存そん档于2022-07-18）.

[sa-2] 339288 Manganese(II) fluoride 98%. Sigma-Aldrich. [2008-06-18].

[dict-3] Ayres, D. C.; Hellier, Desmond. Dictionary of Environmentally Important Chemicals. CRC Press. 1997: 195 [2008-06-18]. ISBN 0-7514-0256-7.

[4] Gmelin Handbook of Inorganic Chemistry. Springer-Verlag. 1977: 5 [2022-07-13]. ISBN 978-0-387-93343-6. （原始げんし内容ないよう存そん档于2022-07-17）（德とく语）.

[5] Nuka, P. Zur Kenntnis der Fluoride des Mangans und Cadmiums. Zeitschrift für anorganische und allgemeine Chemie. 8 April 1929, 180 (1): 235–240 [2022-07-13]. ISSN 0863-1786. doi:10.1002/zaac.19291800125. eISSN 1521-3749. （原始げんし内容ないよう存そん档于2022-07-16）（德とく语）.

[6] Pourroy, G.; Poix, P. New synthesis routes for difluorides MF₂ (M = Fe, Mn, Zn and Ni). Journal of Fluorine Chemistry. February 1989, 42 (2): 257–263 [2022-07-13]. ISSN 0022-1139. doi:10.1016/S0022-1139(00)82754-2. （原始げんし内容ないよう存そん档于2022-07-16）.

[7] Lee, Jeong-Hyeon; Cho, K. K.; Lee, Jeon Ryang; Park, Jae Cheol; Jang, Hansaem; Cho, Beong Ki; Kim, Tae-Won. Manganese Fluoride Nanoparticles Synthesized by Microwave Irradiation Using Ionic Liquid–Ethylene Glycol Mixtures: Room-Temperature Photoluminescence, Crystalline Phase, and Morphology. Crystal Growth & Design. 28 January 2021, 21 (3): 1406–1412 [2022-07-13]. ISSN 1528-7483. doi:10.1021/acs.cgd.0c01522. eISSN 1528-7505. （原始げんし内容ないよう存そん档于2022-07-16）.

[8] Vereshchagin, L. F.; Kabalkina, S. S.; Kotilevets, A. A. Phase transition in MnF₂ at high pressure. Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki. 1965, 49 (6): 1728-1732. ISSN 0044-4510 （俄にわか语）. CODEN ZETFA7.

[9] Massa, W. Zur darstellung und strukturchemie der alkali-tetrafluoromanganate (III): CsMnF₄ und NH₄MnF₄. Inorganic and Nuclear Chemistry Letters. January 1977, 13 (5–6): 253–258 [2022-07-13]. ISSN 0020-1650. doi:10.1016/0020-1650(77)80103-7. （原始げんし内容ないよう存そん档于2018-06-29）（德とく语）.

[10] Rakov, E. G.; Khaustov, S. V.; Ostropikov, V. V. Synthesis of manganese tetrafluoride at atmospheric pressure. Zhurnal Neorganicheskoi Khimii. 1998, 43 (4): 533–537. ISSN 0044-457X （俄にわか语）. CODEN ZNOKAQ.

[11] Mazej, Z. Room temperature syntheses of MnF₃, MnF₄ and hexafluoromanganete(IV) salts of alkali cations. Journal of Fluorine Chemistry. March 2002, 114 (1): 75–80. ISSN 0022-1139. doi:10.1016/S0022-1139(01)00566-8.

[12] Bandemehr, Jascha; Zimmerhofer, Fabian; Ivlev, Sergei I.; Pietzonka, Clemens; Eklund, Kim; Karttunen, Antti J.; Huppertz, Hubert; Kraus, Florian. Syntheses and Characterization of the Mixed-Valent Manganese(II/III) Fluorides Mn₂F₅ and Mn₃F₈. Inorganic Chemistry. 25 August 2021, 60 (17): 12651–12663 [2022-07-13]. ISSN 0020-1669. PMID 34431300. doi:10.1021/acs.inorgchem.1c01833. eISSN 1520-510X. （原始げんし内容ないよう存そん档于2022-07-13）.

[13] Zemva, B.; Zupan, J.; Slivnik, Joze. Xenon fluoride-manganese fluoride reaction. Inst. Jozef Stefan, IJS Rep. 1970, (R585): 1-4. CODEN NJSRA9.

[14] Lutar, Karel; Jesih, Adolf; Žemva, Boris. KrF₂/MnF₄ adducts from KrF₂/MnF₂ interaction In HF As a route to high purity MnF₄. Polyhedron. January 1988, 7 (13): 1217–1219 [2022-07-13]. ISSN 0277-5387. doi:10.1016/S0277-5387(00)81212-7. （原始げんし内容ないよう存そん档于2022-07-13）.

[15] Baratali, Torabali; Abedini, Mansour. The hydrolysis of manganous fluoride. Journal of Inorganic and Nuclear Chemistry. January 1976, 38 (3): 604 [2022-07-13]. ISSN 0022-1902. doi:10.1016/0022-1902(76)80319-3. （原始げんし内容ないよう存そん档于2022-07-13）.

[16] Ippolitov, E. G.; Tripol'skaya, T. A.; Zhigarnovskii, B. M. Study of 3d transition element fluorides. Zhurnal Neorganicheskoi Khimii. 1979, 24 (2): 539–541. ISSN 0044-457X （俄にわか语）. CODEN ZNOKAQ.

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