氧化膦

氧化膦
识别
CAS号ごう	13840-40-9
PubChem	57448882
SMILES	[O-][PH3+];
性せい质
化学かがく式しき	H3OP
摩ま尔质量りょう	50 g·mol−1
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

氧化膦是ぜ一いち种无机化合かごう物ぶつ，化学かがく式しき为H₃PO，它只在ざい稀まれ释的气相中ちゅう稳定，而在液えき相しょう或ある固かた相あい时不稳定。^[1]它作为磷化氢和わ氧气反はん应的产物通どおり过质谱检测得え到いた。^[2]它也是ぜ一いち氧化氮和わ磷化氢在ざい室温しつおん反はん应，生成せいせいP_xH_y固体こたい的中てきちゅう间体。^[3]

参考さんこう文献ぶんけん

^ Greenwood, Norman Neill; Earnshaw, Alan. Chemistry of the elements. 2016. ISBN 978-0-7506-3365-9. OCLC 1040112384 （英えい语）.
^ Hamilton, Peter A.; Murrells, Timothy P. Kinetics and mechanism of the reactions of PH3 with O(3P) and N(4S) atoms. J. Chem. Soc., Faraday Trans. 1985, 2 (81): 1531–1541. doi:10.1039/F29858101531.
^ Zhao, Yi-Lei; Flora, Jason W.; David Thweatt, William; Garrison, Stephen L.; Gonzalez, Carlos; Houk, K. N.; Marquez, Manuel. Phosphine Polymerization by Nitric Oxide: Experimental Characterization and Theoretical Predictions of Mechanism. Inorg. Chem. 2009, 48 (3): 1223–1231. PMID 19102679. doi:10.1021/ic801917a.

[1] Greenwood, Norman Neill; Earnshaw, Alan. Chemistry of the elements. 2016. ISBN 978-0-7506-3365-9. OCLC 1040112384 （英えい语）.

[2] Hamilton, Peter A.; Murrells, Timothy P. Kinetics and mechanism of the reactions of PH3 with O(3P) and N(4S) atoms. J. Chem. Soc., Faraday Trans. 1985, 2 (81): 1531–1541. doi:10.1039/F29858101531.

[3] Zhao, Yi-Lei; Flora, Jason W.; David Thweatt, William; Garrison, Stephen L.; Gonzalez, Carlos; Houk, K. N.; Marquez, Manuel. Phosphine Polymerization by Nitric Oxide: Experimental Characterization and Theoretical Predictions of Mechanism. Inorg. Chem. 2009, 48 (3): 1223–1231. PMID 19102679. doi:10.1021/ic801917a.

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