硝酸しょうさん氙

硝酸しょうさん氙是ぜ一いち种使二に氟化氙与あずか无水硝酸しょうさん反はん应制得とく的てき过渡化合かごう物ぶつ。尽つき管かん二に硝酸しょうさん氙 (Xe(NO₃)₂) 尚なお未み被ひ分ぶん离，它的一いち硝酸しょうさん盐：硝酸しょうさん氟化氙(XeFNO₃)已やめ经进行ぎょう了りょう研究けんきゅう。

制せい备

尝试生せい产二に硝酸しょうさん氙的方法ほうほう： ^[1]

XeF₂ + 2HNO₃ → Xe(NO₃)₂ + 2HF^[2]^[3]

这个反はん应取得しゅとく了りょう红棕色しょく的てき固体こたい，在ざい23 °C 下しも变蓝，持もち续很短たん时间，然しか后きさき猛烈もうれつ分解ぶんかい。^[2]

这个分解ぶんかい反はん应是：

Xe(NO₃)₂ → Xe + O₂NOONO₂ (不ふ稳定的てき氮过氧化物ぶつ)

但ただし是ぜ，确实存在そんざい混合こんごう硝酸しょうさん盐FXeONO₂。 ^[1] 这个化合かごう物ぶつ被ひ称しょう为一硝酸氟化氙^[4] 或ある氟硝酸化さんか氙。^[5]

参考さんこう资料

^ ^1.0 ^1.1 Moran, Matthew D. Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF). McMaster University. 2007: 42, 99–145 [4 Oct 2014]. （原始げんし内容ないよう存そん档 (PDF)于2016-03-03）.
^ ^2.0 ^2.1 Eisenberg, Max; Darryl D. DesMarteau. The reaction of xenon difluoride with some strong oxy-acids. Inorganic and Nuclear Chemistry Letters. 1970, 6 (1): 29–34. ISSN 0020-1650. doi:10.1016/0020-1650(70)80279-3.
^ Zefirov, N. S; Gakh, A. A.; Zhdankin, V. V.; Stang, P. J. Interaction of Fluoroxenonium Triflate, Fluorosulfate, and Νにゅーitrate with Alkenes. Stereochemical Evidence for the Electrophilic Noble Gas Cation Addition to the Carbon-Carbon Double Bond. J. Org. Chem. 1991, 56: 1416–1418. doi:10.1021/jo00004a015.
^ Atta-ur-Rahman. Advances in Organic Synthesis: Modern Organofluorine Chemistry-Synthetic Aspects. Bentham Science Publishers. 2006-01-01: 78 [5 October 2014]. ISBN 9781608051984.
^ Moran, Matthew D.; David S. Brock; Hélène P. A. Mercier; Gary J. Schrobilgen. Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4. Journal of the American Chemical Society. 2010, 132 (39): 13823–13839. ISSN 0002-7863. PMID 20843046. doi:10.1021/ja105618w.

[MoranM2007-1] 1.0 ^1.1 Moran, Matthew D. Synthesis and Structural Characterization of new Xenon(II) Compounds and the Use of a Xenon(II) Cation as an Oxidant for the Preparation of Halogenated Hydrocarbons (PDF). McMaster University. 2007: 42, 99–145 [4 Oct 2014]. （原始げんし内容ないよう存そん档 (PDF)于2016-03-03）.

[Eisenberg1970-2] 2.0 ^2.1 Eisenberg, Max; Darryl D. DesMarteau. The reaction of xenon difluoride with some strong oxy-acids. Inorganic and Nuclear Chemistry Letters. 1970, 6 (1): 29–34. ISSN 0020-1650. doi:10.1016/0020-1650(70)80279-3.

[Zefirov91-3] Zefirov, N. S; Gakh, A. A.; Zhdankin, V. V.; Stang, P. J. Interaction of Fluoroxenonium Triflate, Fluorosulfate, and Νにゅーitrate with Alkenes. Stereochemical Evidence for the Electrophilic Noble Gas Cation Addition to the Carbon-Carbon Double Bond. J. Org. Chem. 1991, 56: 1416–1418. doi:10.1021/jo00004a015.

[Atta-ur-Rahman2006-4] Atta-ur-Rahman. Advances in Organic Synthesis: Modern Organofluorine Chemistry-Synthetic Aspects. Bentham Science Publishers. 2006-01-01: 78 [5 October 2014]. ISBN 9781608051984.

[Moran2010-5] Moran, Matthew D.; David S. Brock; Hélène P. A. Mercier; Gary J. Schrobilgen. Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4. Journal of the American Chemical Society. 2010, 132 (39): 13823–13839. ISSN 0002-7863. PMID 20843046. doi:10.1021/ja105618w.

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