酒石酸 锑钾
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别名 | 吐酒 |
识别 | |
CAS |
28300-74-5 ![]() |
PubChem | 16682736 |
ChemSpider | 17214979 |
SMILES |
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InChI |
|
InChIKey | WBTCZEPSIIFINA-UHFFFAOYSA-J |
EINECS | 234-293-3 |
ChEBI | 2761 |
KEGG | C11340 |
K2Sb2(C4H2O6)2 · 3 H2O | |
667.87 g·mol⁻¹ | |
2.6 g/cm3 | |
8.3 g/100 mL(0 °C) 35.9 g/100 mL(100 °C) | |
危险 | |
警示术语 | R:R20/22 R51/53 |
S:S2 S61 | |
![]() ![]() | |
LD50(
|
110 mg/kg |
催吐作用
[编辑]![](https://upload.wikimedia.org/wikipedia/commons/thumb/f/fc/Brechweinstein.jpg/130px-Brechweinstein.jpg)
药用
[编辑]毒性
[编辑]制 取
[编辑]参考 资料
[编辑]- ^ McCallum, RI. President's address. Observations upon antimony. Proceedings of the Royal Society of Medicine. 1977, 70 (11): 756–63. PMC 1543508
. PMID 341167.
- ^ Thomson, SC. Antimonyall Cupps: Pocula Emetica or Calices Vomitorii. Proceedings of the Royal Society of Medicine. 1926, 19 (Sect Hist Med): 122.2–128. PMC 1948687
. PMID 19985185.
- ^ Weiss, S.; Hatcher, RA. The Mechanism of the Vomiting Induced by Antimony and Potassium Tartrate (Tartar Emetic). Journal of Experimental Medicine. 1922, 37 (1): 97–111. PMC 2128404
. PMID 19868716. doi:10.1084/jem.37.1.97.
- ^ Poulin, B.; Lefebvre, G. t.; McNeil, R. Effect and Efficiency of Tartar Emetic in Determining the Diet of Tropical Land Birds. The Condor. 1994, 96 (1): 98–104. JSTOR 1369067. doi:10.2307/1369067.
- ^ Carlisle, J. D.; Holberton, R. L. Relative Efficiency of Fecal versus Regurgitated Samples for Assessing Diet and the Deleterious Effects of a Tartar Emetic on Migratory Birds. Journal of Field Ornithology. 2006, 77 (2): 126–135. JSTOR 27639314. doi:10.1111/j.1557-9263.2006.00032.x.
- ^ Diamond, Antony W.; Fayad, V. C.; McKinley, Peter S. Commentary: Ipecac: An Improved Emetic for Wild Birds. Journal of Field Ornithology. 2007, 78 (4): 436–439. JSTOR 27715221. doi:10.1111/j.1557-9263.2007.00136.x.
- ^ 7.0 7.1 Low, George C. The history of the use of intravenous injections of tartar emetic (Antimonium tartaratum) in tropical medicine. Transactions of the Royal Society of Tropical Medicine and Hygiene. 1916, 10 (2): 37. doi:10.1016/S0035-9203(16)90068-3.
- ^ Navarro, Maribel; Gabbiani, Chiara; Messori, Luigi; Gambino, Dinorah. Metal-based drugs for malaria, trypanosomiasis and leishmaniasis: Recent achievements and perspectives. Drug Discovery Today. 2010, 15 (23–24): 1070–8. PMID 20974285. doi:10.1016/j.drudis.2010.10.005.
- ^ Christopherson, J.B. The Successful Use of Antimony in Bilharziosis. The Lancet. 1918, 192 (4958): 325. doi:10.1016/S0140-6736(01)02807-0.
- ^ Crichton-Harris, Ann. Poison in small measure: Dr. Christopherson and the cure for bilharzia. 2009-07-15 [2012-08-13]. ISBN 978-90-04-17541-9. (
原始 内容 存 档于2019-06-14). - ^ Sabah, A.A.; Fletcher, Cathy; Webbe, G.; Doenhoff, M.J. Schistosoma mansoni: Chemotherapy of infections of different ages. Experimental Parasitology. 1986, 61 (3): 294–303. PMID 3086114. doi:10.1016/0014-4894(86)90184-0.
- ^ T'AO, SC. Cardiac manifestations of the toxic action of potassium antimony tartrate in schistosomiasis patients: paroxysmal ventricular tachycardia and fibrillation.. Chinese medical journal (Peking, China : 1932). 1957-05, 75 (5): 365–78. PMID 13447130.
- ^ Hagan, Paul. Schistosomiasis – a rich vein of research. Parasitology. 2009, 136 (12): 1611–9. PMID 19691867. doi:10.1017/S003118200999093X.
- ^ Publishers, Bentham Science. The Antimonials. Current Medicinal Chemistry. 1996-10: 304–305 [2012-08-13]. (
原始 内容 存 档于2014-04-07). - ^ Winship, K. A. Toxicity of antimony and its compounds. Adverse drug reactions and acute poisoning reviews. 1987, 6 (2): 67–90. PMID 3307336.
- ^ Lauwers, LF; Roelants, A; Rosseel, PM; Heyndrickx, B; Baute, L. Oral antimony intoxications in man.. Critical care medicine. 1990-03, 18 (3): 324–6. PMID 2302961. doi:10.1097/00003246-199003000-00017.
- ^ Cabot, Richard C.; Harris, Nancy Lee; Shepard, Jo-Anne O.; Rosenberg, Eric S.; Cort, Alice M.; Ebeling, Sally H.; Peters, Christine C.; MacÍas Konstantopoulos, Wendy; Burns Ewald, Michele. Case 22-2012. New England Journal of Medicine. 2012, 367 (3): 259. doi:10.1056/NEJMcpc1111580.
- ^ Knapp, Fr. Zur Bildungsgeschichte des Brechweinsteins. Annalen der Pharmacie. 1839, 32: 76. doi:10.1002/jlac.18390320107.
拓 展 阅读
[编辑]- Priesner, Claus. Basilius Valentinus und die Labortechnik um 1600. Berichte zur Wissenschaftsgeschichte. 1997, 20 (2–3): 159. doi:10.1002/bewi.19970200205.
- Geoffroy, M.; Stack, T. Observations on the Effects of the Vitrum Antimonii Ceratum, by Mons. Geoffroy, of the Royal Academy of Sciences, and F. R. S. Translated from the French by Tho. Stack, M. D. F. R. S. Philosophical Transactions. 1751, 47: 273–278. JSTOR 105054. doi:10.1098/rstl.1751.0042.
- Berzelius, Jöns Jacob. Lehrbuch der Chemie. 1824 [2012-08-13]. (
原始 内容 存 档于2019-06-14). - Copus, Martinus. Das Spißglas in ein Glas gegossen, das man Vitrum Antimonii nennt, ein wahrhafftige Gift vnd gantzgeferliche Artzney sey. 1569.
- The Technologist. 1861 [2012-08-13]. (
原始 内容 存 档于2019-06-14). - Captain Cook's Antimony Cup (PDF). Vesalius, VII, 2. 2001: 62–64.
- Schneider, R. Ueber einige Antimon-Verbindungen. Annalen der Physik und Chemie. 1859, 184 (11): 407. Bibcode:1859AnP...184..407S. doi:10.1002/andp.18591841104.
- Groschuff, E. Reines Antimon. Zeitschrift für anorganische und allgemeine Chemie. 1918, 103: 164. doi:10.1002/zaac.19181030109.
- Soubeiran, E.; Capitaine, H. Zur Geschichte der Weinsteinsäure. Journal für Praktische Chemie. 1840, 19: 435. doi:10.1002/prac.18400190171.
- Pfaff, C. H. Ueber Antimon-Wasserstoffgas und die davon abhängige Unsicherheit des von James Marsh entdeckten Verfahrens zur Entdeckung des Arseniks. Archiv der Pharmazie. 1838, 64 (2): 169. doi:10.1002/ardp.18380640215.
- Zimmermann, E. Das Antimon in der Chemotherapie. Klinische Wochenschrift. 1930, 9: 27. doi:10.1007/BF01740712.
- Gress, Mary E.; Jacobson, Robert A. X-ray and white radiation neutron diffraction studies of optically active potassium antimony tartrate, K2Sb2(d-C4H2O6)2·3H2O (tarter emetic). Inorganica Chimica Acta. 1974, 8: 209. doi:10.1016/S0020-1693(00)92617-3.