氟正离子
(重定 向 自 鉘)
氟正离子 | |||
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IUPAC Fluoronium | |||
Fluoranium[1] | |||
识别 | |||
CAS |
12206-67-6 ![]() | ||
ChemSpider | 19122106 | ||
SMILES |
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InChI |
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InChIKey | YNESUKSMQODWNS-UHFFFAOYAK | ||
ChEBI | 50314 | ||
H2F+ | |||
21.01428 g·mol⁻¹ | |||
氟正
- HF + H+ → H2F+
- 3HF ⇌ H2F+ + HF2−
二氢氟阳离子可以在氟锑
2F−
11阴离
![](https://upload.wikimedia.org/wikipedia/commons/thumb/f/ff/Lectka-fluoronium.png/220px-Lectka-fluoronium.png)
参 见
[编辑]参考 资料
[编辑]- ^ Fluoronium (CHEBI:50314). Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. [2011-10-12]. (
原始 内容 存 档于2016-03-16). - ^
化學 命名 原則 第 四 版 .國立 編 譯 館 . 2004 [2021-11-19]. (原始 内容 存 档于2021-02-10). - ^ Esteves, Pierre M.; Ramírez-Solís, Alejandro; Mota, Claudio J. A. The Nature of Superacid Electrophilic Species in HF/SbF5: A Density Functional Theory Study. Journal of the American Chemical Society. March 2002, 124 (11): 2672–2677. ISSN 0002-7863. PMID 11890818. doi:10.1021/ja011151k.
- ^ Mootz, Dietrich; Bartmann, Klemens. The Fluoronium Ions H2F+ and H3F2+: Characterization by Crystal Structure Analysis. Angewandte Chemie. 1988, 27 (3): 391–392. doi:10.1002/anie.198803911.
- ^ Diercksen, G. H. F.; von Niessen, W.; Kraemer, W. P. SCF LCGO MO studies on the fluoronium ion FH+
2 and its hydrogen bonding interaction with hydrogen fluoride FH. Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta). 1973, 31 (3): 205–214. doi:10.1007/BF00526510. - ^ Hämmerling, Sebastian; Thiele, Günther; Steinhauer, Simon; Beckers, Helmut; Müller, Carsten; Riedel, Sebastian. A Very Strong Methylation Agent: [Me2Cl][Al(OTeF5)4]. Angewandte Chemie International Edition. 2019, 58 (29): 9807–9810 [2024-01-19]. ISSN 1521-3773. PMID 31050103. S2CID 143434865. doi:10.1002/anie.201904007. (
原始 内容 存 档于2023-04-14) (英 语). - ^ Pitts, Cody Ross; Holl, Maxwell Gargiulo; Lectka, Thomas. Spectroscopic Characterization of a [C−F−C]+ Fluoronium Ion in Solution. Angewandte Chemie International Edition. 2018-02-12, 57 (7): 1924–1927. PMID 29316122. doi:10.1002/anie.201712021 (
英 语).
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