二 甲 基 镁
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IUPAC Dimethylmagnesium | |
识别 | |
CAS |
2999-74-8 ![]() |
PubChem | 18141 |
ChemSpider | 10430979 |
SMILES |
|
C2H6Mg | |
54.37 g·mol−1 | |
0.96 g/cm3 | |
制 备
[编辑]二甲基镁可以由不少于化学计量比的
- 2 CH3MgX + dioxane ⇌ (CH3)2Mg + MgX2(dioxane)
二卤化镁和二恶烷的配合物是一种沉淀,
钙、镁以及碘甲烷
结构
[编辑]二甲基镁的结构由X
参考 文献
[编辑]- ^ Cope, A. C. The Preparation of Dialkylmagnesium Compounds from Grignard Reagents. J. Am. Chem. Soc. 1935, 57 (11): 2238–2240. doi:10.1021/ja01314a059.
- ^ Anteunis, M. Studies of the Grignard Reaction. II. Kinetics of the Reaction of Dimethylmagnesium with Benzophenone and of Methylmagnesium Bromide-Magnesium Bromide with Pinacolone. J. Org. Chem. 1962, 27 (2): 596–598. doi:10.1021/jo01049a060.
- ^ [[1],
第 215頁 ,載 於Google圖書 Houben-Weyl Methods of Organic Chemistry Vol. XIII/2a, 4th Edition Organometallic Compounds of Group II of the Periodic Table (except mercury)], Georg Thieme Verlag. 2014: p. 215, (德 文 ) - ^ Jane E. Macintyre, [[2],
第 2273頁 ,載 於Google圖書 Dictionary of Organometallic Compounds], CRC Press. 1994: p. 2273, (德 文 ) - ^ Weiss, E. Die Kristallstruktur des Dimethylmagnesiums. J. Organomet. Chem. 1964, 2 (4): 314–321. doi:10.1016/S0022-328X(00)82217-2.
- ^ Snow, A.I.; Rundle, R.E. Structure of Dimethylberyllium. Acta Crystallographica. 1951, 4: 348–52. doi:10.1107/S0365110X51001100.