叔丁硫醇
tert-Butylthiol | |
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IUPAC 2-Methylpropane-2-thiol | |
别名 | t-BuSH 2- 叔丁 |
识别 | |
缩写 | TBM |
CAS |
75-66-1 ![]() |
PubChem | 6387 |
ChemSpider | 6147 |
SMILES |
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InChI |
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InChIKey | WMXCDAVJEZZYLT-UHFFFAOYAT |
C4H10S | |
90.19 g·mol−1 | |
无色 | |
0.8 g/mL | |
熔点 | −0.50 °C(272.65 K) |
62—65 °C(335—338 K) | |
叔丁硫醇
制 备
[编辑]- t-BuMgCl + S → t-BuSMgCl
- t-BuSMgCl + H2O → t-BuSH + Mg(OH)Cl
参考 文献
[编辑]- ^ tert-butyl mercaptan. thegoodscentscompany.com. [2018-04-12]. (
原始 内容 存 档于2019-01-20). - ^ Gumbmann, M. R.; Burr, H. K. Volatile Sulfur Compounds in Potatoes. Journal of Food and Agricultural Chemistry. 1964, 12 (5): 404–408. doi:10.1021/jf60135a004.
- ^ Dobbin, Leonard. On tertiary Butyl Mercaptan. Journal of the Chemical Society, Transactions. 1890, 57: 639–643. doi:10.1039/ct8905700639.
- ^ Rheinboldt, Heinrich; Mott, Friedrich; Motzkus, Erwin; A. D. McMaster; B. M. Mattson; S. T. Michel. Tertiäres Butylmercaptan. Journal fuer Praktische Chemie (Leipzig). 1932, 134 (9–12): 257–281. doi:10.1002/prac.19321340901.
- ^ Schulze, W.A.; Lyon, J.P. & Short, G.H. Synthesis of Tertiary Alkyl Mercaptans. Industrial and Engineering Chemistry (American Chemical Society). 1948, 40 (12): 2308–2313. doi:10.1021/ie50468a019.