猕猴桃もも碱

猕猴桃もも碱
	IUPAC名めい; (7S)-4,7-Dimethyl-6,7-dihydro-5H-cyclopenta[c]pyridine
识别
CAS号ごう	524-03-8
PubChem	68231
ChemSpider	61533
SMILES	C[C@@H](CC1)C2=C1C(C)=CN=C2;
InChI	1/C10H13N/c1-7-3-4-9-8(2)5-11-6-10(7)9/h5-7H,3-4H2,1-2H3/t7-/m0/s1;
InChIKey	ZHQQRIUYLMXDPP-ZETCQYMHBZ
Beilstein	81308
ChEBI	2443
KEGG	C09910
性せい质
化学かがく式しき	C10H13N
摩ま尔质量りょう	147.22 g·mol−1
熔点	25 °C（298 K）
沸点ふってん	100 - 103 °C（270 K）
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

猕猴桃もも碱（英語えいご：Actinidine）是ぜ一いち种环烯醚萜化合かごう物ぶつ，由ゆかり多た种植物しょくぶつ和わ动物在ざい自然しぜん界かい中ちゅう产生。它是第だい一个被发现的环戊单萜生物碱。^[1]它是可か从缬草（Valeriana officinalis）根ね^[2]和わ葛かずら枣猕猴桃（Actinidia polygama）以及几种处于幼虫ようちゅう和わ成虫せいちゅう阶段的てき昆虫こんちゅう中ちゅう提ひさげ取的とりてき化合かごう物ぶつ之の一いち。^[3]猕猴桃もも碱是一いち种猫引诱剂，其作用よう类似于猫ねこ薄荷はっか中なか的てき活性かっせい化合かごう物ぶつ荆芥内ない酯。^[4]

某ぼう些竹たけ节虫物もの种，包括ほうかつMegacrania batesii和わ津田つだ氏し大だい头䗛（Megacrania tsudai），具有ぐゆう化学かがく防御ぼうぎょ机つくえ制せい，当とう受到捕食ほしょく者しゃ威い胁时，其前ぜん胸むね腺せん会かい分泌ぶんぴつ含猕猴桃碱的物ぶつ质。^[5]

生物せいぶつ合成ごうせい

下しも图显示しめせ了りょう从L-香こう茅ちがや醛中ちゅう生物せいぶつ合成ごうせい猕猴桃もも碱的潜在せんざい方法ほうほう。^[6]

参考さんこう资料

^ Tsutsui, Minoru; Tsutsui, Ethel Ashworth. Diterpenoids. Chemical Reviews. 1959, 59 (6): 1031–1075 [2024-03-15]. doi:10.1021/cr50030a003. （原始げんし内容ないよう存そん档于2022-06-17）.
^ Janot MM, Guilhem J, Contz O, Venera G, Cionga E. Contribution to the study of valerian alcaloids (Valeriana officinalis L.): actinidine and naphthyridylmethylketone, a new alkaloid. Ann. Pharm. Fr. 1979, 37 (9–10): 413–20. PMID 547813 （法ほう语）.
^ Weibel DB, Oldham NJ, Feld B, Glombitza G, Dettner K, Boland W. Iridoid biosynthesis in staphylinid rove beetles (Coleoptera: Staphylinidae, Philonthinae). Insect Biochemistry and Molecular Biology. 2001, 31 (6–7): 583–591. PMID 11267897. doi:10.1016/s0965-1748(00)00163-6.
^ Lichman, Benjamin R.; Godden, Grant T.; Hamilton, John P.; Palmer, Lira; Kamileen, Mohamed O.; Zhao, Dongyan; Vaillancourt, Brieanne; Wood, Joshua C.; Sun, Miao; Kinser, Taliesin J.; Henry, Laura K. The evolutionary origins of the cat attractant nepetalactone in catnip. Science Advances. 2020-05-01, 6 (20): eaba0721. Bibcode:2020SciA....6..721L. ISSN 2375-2548. PMC 7220310 . PMID 32426505. doi:10.1126/sciadv.aba0721  （英えい语）.
^ Wu, I-Hsin; Liu, Hsui-Huei; Chen, Yu-Yen; Tsai, Cheng-Lung; Yu, Yi-Ching; Hsiao, Chung-Yi; Yeh, Wen-Bin. Life cycles, phenology and genetic structure of endangered Megacrania tsudai Shiraki (Phasmatodea: Phasmatidae): Male individuals from a geographic parthenogenesis species. Entomological Science. 2020, 23 (2): 183–192. S2CID 216322536. doi:10.1111/ens.12410.
^ Funayama, Shinji; Cordell, Geoffrey A. (编). 14: Alkaloids Derived from Terpenoids. Alkaloids. Academic Press. 2015: 233–255.

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[Tsutsui1959-1] Tsutsui, Minoru; Tsutsui, Ethel Ashworth. Diterpenoids. Chemical Reviews. 1959, 59 (6): 1031–1075 [2024-03-15]. doi:10.1021/cr50030a003. （原始げんし内容ないよう存そん档于2022-06-17）.

[2] Janot MM, Guilhem J, Contz O, Venera G, Cionga E. Contribution to the study of valerian alcaloids (Valeriana officinalis L.): actinidine and naphthyridylmethylketone, a new alkaloid. Ann. Pharm. Fr. 1979, 37 (9–10): 413–20. PMID 547813 （法ほう语）.

[3] Weibel DB, Oldham NJ, Feld B, Glombitza G, Dettner K, Boland W. Iridoid biosynthesis in staphylinid rove beetles (Coleoptera: Staphylinidae, Philonthinae). Insect Biochemistry and Molecular Biology. 2001, 31 (6–7): 583–591. PMID 11267897. doi:10.1016/s0965-1748(00)00163-6.

[4] Lichman, Benjamin R.; Godden, Grant T.; Hamilton, John P.; Palmer, Lira; Kamileen, Mohamed O.; Zhao, Dongyan; Vaillancourt, Brieanne; Wood, Joshua C.; Sun, Miao; Kinser, Taliesin J.; Henry, Laura K. The evolutionary origins of the cat attractant nepetalactone in catnip. Science Advances. 2020-05-01, 6 (20): eaba0721. Bibcode:2020SciA....6..721L. ISSN 2375-2548. PMC 7220310 . PMID 32426505. doi:10.1126/sciadv.aba0721  （英えい语）.

[Wu2020-5] Wu, I-Hsin; Liu, Hsui-Huei; Chen, Yu-Yen; Tsai, Cheng-Lung; Yu, Yi-Ching; Hsiao, Chung-Yi; Yeh, Wen-Bin. Life cycles, phenology and genetic structure of endangered Megacrania tsudai Shiraki (Phasmatodea: Phasmatidae): Male individuals from a geographic parthenogenesis species. Entomological Science. 2020, 23 (2): 183–192. S2CID 216322536. doi:10.1111/ens.12410.

[6] Funayama, Shinji; Cordell, Geoffrey A. (编). 14: Alkaloids Derived from Terpenoids. Alkaloids. Academic Press. 2015: 233–255.

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