硫代甲かぶと醛

硫代甲かぶと醛
别名	Methanethial
识别
CAS号ごう	865-36-1
PubChem	79115
ChemSpider	71446
SMILES	C=S;
InChI	1S/CH2S/c1-2/h1H2;
InChIKey	DBTDEFJAFBUGPP-UHFFFAOYSA-N
EINECS	200-454-1
性せい质
化学かがく式しき	CH; 2S
摩ま尔质量りょう	46.09 g·mol⁻¹
外そと观	未知みち
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

硫代甲かぶと醛（英語えいご：Thioformaldehyde）是ぜ一いち種しゅ有機ゆうき硫化りゅうか合あい物ぶつ，化學かがく式しき為ためCH
2S。

簡介

硫代甲かぶと醛的結構けっこう式しき首くび次じ由よし意い大利おおとし化學かがく家西いえにし爾なんじ維奧·貝かい茲（Silvio Bezzi）確認かくにん。^[1]一個人工製備的方法是在10 K溫度おんど的てき氬基質しつ中ちゅう對たい三硫代碳酸甲酯C
2H
2S
3進行しんこう光ひかり分解ぶんかい作用さよう。^[2]

此化合かごう物ぶつ在日ざいにち常つね環境かんきょう中ちゅう並なみ不穩ふおん定じょう，極ごく易えき形成けいせい其低てい聚物，即そく具有ぐゆう相しょう同どう實驗じっけん式しき的てき1,3,5-三硫雜環己烷，因いん此十じゅう分ふん罕見。然しか而在星ほし際ぎわ物質ぶっしつ中ちゅう則のり能のう觀かん察到其存在そんざい，^[3]鼓つづみ勵了對たい其性質的しつてき研究けんきゅう。^[4]藉紅べに外がい光こう譜ふ儀ぎ可か得知とくち其存在そんざい於緻密ちみつ高速こうそく雲くもCO-0.40-0.22等とう星ほし際ぎわ雲くも，^[5]以及海うみ爾なんじ-博ひろし普ひろし彗星すいせい之これ彗髮。^[6]^[7]

由よし於雙鍵かぎ原理げんり，硫代甲かぶと醛傾向こう形成けいせい鏈狀或ある環狀かんじょう結構けっこう。已やめ知ち其存在そんざい於數種しゅ配はい位い化合かごう物ぶつ中なか，包括ほうかつ以下いか的てきOs(SCH
2)(CO)
2(PPh
3)
2。^[8]

硫代甲かぶと醛之製せい備
鎢-硫代甲かぶと醛配合はいごう物ぶつ之の形成けいせい
鋨-硫代甲かぶと醛配合はいごう物ぶつ之の形成けいせい

參考さんこう

^ Croatto, Ugo. Treccani , 编. BEZZI, Silvio. Dizionario Biografico degli Italiani. 1967, 9 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.
^ Torres, M.; Safarik, I.; Clement, A.; Strausz, O. P. The generation and vibrational spectrum of matrix isolated thioformaldehyde and dideuterothioformaldehyde (pdf). Canadian Journal of Chemistry. 1982, 60 (10): 1187–1191 [2017-09-17]. doi:10.1139/v82-176.
^ Despois, D., "Radio Line Observations of Molecular and Isotopic Species in Comet C/1995 O1 (Hale-Bopp) Implications on the Interstellar Origin of Cometary Ices", Earth, Moon, Planets 1999, 79, 103-124.
^ Clouthier, D. J.; Ramsay, D. A. The Spectroscopy of Formaldehyde and Thioformaldehyde. Annual Review of Physical Chemistry. 1983, 34: 31–58. Bibcode:1983ARPC...34...31C. doi:10.1146/annurev.pc.34.100183.000335.
^ Oka, Tomoharu; Mizuno, Reiko; Miura, Kodai; Takekawa, Shunya. The American Astronomical Society , 编. Signature of an Intermediate-Mass Black Hole in the Central Zone of our Galaxy. The Astrophysical Journal Letters. 2015-12-28, 816 (1): L7 [2017-09-14]. Bibcode:2016ApJ...816L...7O. arXiv:1512.04661 . doi:10.3847/2041-8205/816/1/L7. （原始げんし内容ないよう存そん档于2017-09-12）.
^ Woodney, L. M.; A'Hearn, M. F.; McMullin, J.; Samarasinha, N. Sulfur Chemistry at Millimeter Wavelengths in C/Hale-Bopp. Earth, Moon, and Planets. 1997-07, 78 (1-3): 69—70 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.
^ Despois, D. radio Line Observations of Molecular and Isotopic Species in Comet C/1995 O1 (Hale-Bopp) Implications on the Interstellar Origin of Cometary Ices. Earth, Moon, and Planets. 1997-09, 79 (1-3): 103–124 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.
^ Schenk, Wolfdieter A. The coordination chemistry of small sulfur-containing molecules: A personal perspective. Dalton Trans. 2011, 40 (6): 1209–1219. PMID 21088787. doi:10.1039/C0DT00975J.

[1] Croatto, Ugo. Treccani , 编. BEZZI, Silvio. Dizionario Biografico degli Italiani. 1967, 9 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.

[2] Torres, M.; Safarik, I.; Clement, A.; Strausz, O. P. The generation and vibrational spectrum of matrix isolated thioformaldehyde and dideuterothioformaldehyde (pdf). Canadian Journal of Chemistry. 1982, 60 (10): 1187–1191 [2017-09-17]. doi:10.1139/v82-176.

[3] Despois, D., "Radio Line Observations of Molecular and Isotopic Species in Comet C/1995 O1 (Hale-Bopp) Implications on the Interstellar Origin of Cometary Ices", Earth, Moon, Planets 1999, 79, 103-124.

[4] Clouthier, D. J.; Ramsay, D. A. The Spectroscopy of Formaldehyde and Thioformaldehyde. Annual Review of Physical Chemistry. 1983, 34: 31–58. Bibcode:1983ARPC...34...31C. doi:10.1146/annurev.pc.34.100183.000335.

[oka-5] Oka, Tomoharu; Mizuno, Reiko; Miura, Kodai; Takekawa, Shunya. The American Astronomical Society , 编. Signature of an Intermediate-Mass Black Hole in the Central Zone of our Galaxy. The Astrophysical Journal Letters. 2015-12-28, 816 (1): L7 [2017-09-14]. Bibcode:2016ApJ...816L...7O. arXiv:1512.04661 . doi:10.3847/2041-8205/816/1/L7. （原始げんし内容ないよう存そん档于2017-09-12）.

[6] Woodney, L. M.; A'Hearn, M. F.; McMullin, J.; Samarasinha, N. Sulfur Chemistry at Millimeter Wavelengths in C/Hale-Bopp. Earth, Moon, and Planets. 1997-07, 78 (1-3): 69—70 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.

[7] Despois, D. radio Line Observations of Molecular and Isotopic Species in Comet C/1995 O1 (Hale-Bopp) Implications on the Interstellar Origin of Cometary Ices. Earth, Moon, and Planets. 1997-09, 79 (1-3): 103–124 [2017-09-16]. （原始げんし内容ないよう存そん档于2017-09-18）.

[8] Schenk, Wolfdieter A. The coordination chemistry of small sulfur-containing molecules: A personal perspective. Dalton Trans. 2011, 40 (6): 1209–1219. PMID 21088787. doi:10.1039/C0DT00975J.

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