氯酸鋰
氯酸鋰 | |||
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别名 | |||
识别 | |||
CAS |
36355-96-1 ![]() | ||
PubChem | 61612 | ||
ChemSpider | 55520 | ||
SMILES |
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InChI |
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LiClO3 | |||
90.39 g·mol⁻¹ | |||
熔点 | 127.6-129 °C[1][2][3] | ||
270 °C ( | |||
313.5 g·100 ml (18 °C)[4] | |||
其他阴离 |
氯化鋰 | ||
其他阳离 |
氯酸钠 氯酸钾 氯酸銣 氯酸銫 | ||
氯酸鋰
制 備
[编辑]- Li2CO3 + HClO3 → 2LiClO3 + CO2↑
- Li2SO4 + Ba(ClO3)2 → LiClO3 + BaSO4↓
反應
[编辑]- 2LiClO3 → 2LiCl + 3O2↑
- 4LiClO3 → LiCl + 3LiClO4
用途
[编辑]參考 文獻
[编辑]- ^ S. S. Wang, D. N. Bennion: "The Electrochemistry of Molten Lithium Chlorate and Its Possible Use with Lithium in a Battery" in J. Electrochem. Soc. 1983, 130(4), S. 741-747. Abstract
- ^ A. N. Campbell, E. M. Kartzmark, W. B. Maryk: "The Systems Sodium Chlorate - Water - Dioxane and Lithium Chlorate - Water - Dioxane, at 25°" in Can. J. Chem. 1966, 44, S. 935-937. Volltext[
永久 失效 連結 ] - ^ http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN000130000004000741000001&idtype=cvips&gifs=yes&ref=no
- ^ 4.0 4.1 4.2 4.3 4.4 R. Abegg, F. Auerbach, I. Koppel: Handbuch der anorganischen Chemie. Verlag S. Hirzel, 1908, 2. Band, 1. Teil, S. 136. Volltext
- ^ E.-C. Koch: "Special Materials in Pyrotechnics: III. Application of Lithium and its Compounds in Energetic Systems" in Propellants, Explosives, Pyrotechnics 2004, 29(2). S. 67-80. doi:10.1002/prep.200400032
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