铂酸锂

铂酸锂
	IUPAC名めい; Lithium platinate
识别
CAS号ごう	37363-24-9
性せい质
化学かがく式しき	Li2PtO3
摩ま尔质量りょう	256.966 g·mol⁻¹
外そと观	黄色おうしょく晶あきら体からだ
能のう隙すき	2.3 eV eV
结构
晶あきら体からだ结构	单斜晶あきら系けい，C2/m
晶あきら格かく常数じょうすう	a = 5.1836(2) Å, b = 8.9726(3) Å, c = 5.1113(1) Å
晶あきら格かく常数じょうすう	αあるふぁ = 90°, βべーた = 109.864(2)°, γがんま = 90°
相あい关物质
其他阴离子こ	铱酸锂; 钌酸锂
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

铂酸锂是ぜ一いち种无机化合かごう物ぶつ，化学かがく式しき为Li₂PtO₃。它具有ぐゆう层状蜂はち窝晶体たい结构，为带隙2.3eV的てき半はん导体，可か由ゆかり铂和わ碳酸锂于600°C反はん应得到いた。^[2]铂酸锂是潜在せんざい的てき锂离子こ电池电极材料ざいりょう，^[1]^[3]但ただし因よし铂的价格相しょう比ひ于Li₂MnO₃太ふとし贵而无实际应用よう。^[4]

参考さんこう文献ぶんけん

^ ^1.0 ^1.1 ^1.2 O'Malley, Matthew J.; Verweij, Henk; Woodward, Patrick M. Structure and properties of ordered Li₂IrO₃ and Li₂PtO₃. Journal of Solid State Chemistry. 2008, 181 (8): 1803. doi:10.1016/j.jssc.2008.04.005.
^ Kasuya, Ryo; Miki, Takeshi; Morikawa, Hisashi; Tai, Yutaka. Synthesis of alkali metal platinates and their dissolution behavior in hydrochloric acid. Journal of the Ceramic Society of Japan. 2013, 121 (1418): 884. doi:10.2109/jcersj2.121.884.
^ Okada, Shigeto; Yamaki, Jun-Ichi; Asakura, Kaoru; Ohtsuka, Hideaki; Arai, Hajime; Tobishima, Shin-Ichi; Sakurai, Yoji. Cathode characteristics of layered rocksalt oxide, Li₂PtO₃. Electrochimica Acta. 1999, 45: 329. doi:10.1016/S0013-4686(99)00214-5.
^ Yoshio, Masaki; Brodd, Ralph J.; Kozawa, Akiya. Lithium-Ion Batteries: Science and Technologies. Springer Science & Business Media. 17 July 2010: 10 [2017-08-05]. ISBN 978-0-387-34445-4. （原始げんし内容ないよう存そん档于2017-03-21）.

[r1-1] 1.0 ^1.1 ^1.2 O'Malley, Matthew J.; Verweij, Henk; Woodward, Patrick M. Structure and properties of ordered Li₂IrO₃ and Li₂PtO₃. Journal of Solid State Chemistry. 2008, 181 (8): 1803. doi:10.1016/j.jssc.2008.04.005.

[2] Kasuya, Ryo; Miki, Takeshi; Morikawa, Hisashi; Tai, Yutaka. Synthesis of alkali metal platinates and their dissolution behavior in hydrochloric acid. Journal of the Ceramic Society of Japan. 2013, 121 (1418): 884. doi:10.2109/jcersj2.121.884.

[3] Okada, Shigeto; Yamaki, Jun-Ichi; Asakura, Kaoru; Ohtsuka, Hideaki; Arai, Hajime; Tobishima, Shin-Ichi; Sakurai, Yoji. Cathode characteristics of layered rocksalt oxide, Li₂PtO₃. Electrochimica Acta. 1999, 45: 329. doi:10.1016/S0013-4686(99)00214-5.

[4] Yoshio, Masaki; Brodd, Ralph J.; Kozawa, Akiya. Lithium-Ion Batteries: Science and Technologies. Springer Science & Business Media. 17 July 2010: 10 [2017-08-05]. ISBN 978-0-387-34445-4. （原始げんし内容ないよう存そん档于2017-03-21）.

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