二に十じゅう四よん碳化钾

二に十じゅう四よん碳化钾
识别
CAS号ごう	12100-36-6
性せい质
化学かがく式しき	C24K
摩ま尔质量りょう	327.36 g·mol−1
外そと观	深ふか蓝色
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

二に十じゅう四よん碳化钾是ぜ一种石墨插层化合物，化学かがく式しき为KC₂₄。它可由ゆかり八はち碳化钾和わ石墨せきぼく在ざい350~450 °C共きょう热反应制得え，^[2]或ある由ゆかり钾和わ石墨せきぼく在ざい真空しんくう中ちゅう于350 °C反はん应得到いた。^[1]它在Co(C₂H₄)(PMe₃)₃催化下和したお锂在ざい戊つちのえ烷中ちゅう反はん应，可か以得到いたLi_2.67KC₂₄。^[3]

参考さんこう文献ぶんけん[编辑]

^ ^1.0 ^1.1 Ichikawa, Masaru; Inoue, Yukio; Tamaru, Kenzi. Catalytic hydrogenation of benzene by graphite-potassium lamellar compounds C8K and C24K. Journal of the Chemical Society, Chemical Communications (1972), (16), 928-929. doi:10.1039/C39720000928.
^ Akuzawa, Noboru; Kunihashi, Yoji; Sato, Yuki; Tsuchiya, Ken-ichi; Matsumoto, Rika. Effect of sorbed molecules on the resistivity of alkali metal-graphite intercalation compounds. Journal of Solid State Chemistry (2007), 180(3), 894-901. doi:10.1016/j.jssc.2006.12.019.
^ Klein, H. F.; Dreisbach, M.; Gass, M.; Cordier, G. Saturation intercalation - preparation of first stacked lithium/potassium graphitides. Materials Science Forum (1992), 91-93: 35-40. doi:10.4028/www.scientific.net/MSF.91-93.35.

拓つぶせ展てん阅读[编辑]

Shioyama, Hiroshi. The reaction of potassium-graphite intercalation compounds with halogens（日にち語ご）. Tanso, 2002. 203. 120-122. ISSN 0371-5345.

[Ichikawa-1] 1.0 ^1.1 Ichikawa, Masaru; Inoue, Yukio; Tamaru, Kenzi. Catalytic hydrogenation of benzene by graphite-potassium lamellar compounds C8K and C24K. Journal of the Chemical Society, Chemical Communications (1972), (16), 928-929. doi:10.1039/C39720000928.

[2] Akuzawa, Noboru; Kunihashi, Yoji; Sato, Yuki; Tsuchiya, Ken-ichi; Matsumoto, Rika. Effect of sorbed molecules on the resistivity of alkali metal-graphite intercalation compounds. Journal of Solid State Chemistry (2007), 180(3), 894-901. doi:10.1016/j.jssc.2006.12.019.

[3] Klein, H. F.; Dreisbach, M.; Gass, M.; Cordier, G. Saturation intercalation - preparation of first stacked lithium/potassium graphitides. Materials Science Forum (1992), 91-93: 35-40. doi:10.4028/www.scientific.net/MSF.91-93.35.

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