羽はね扇おうぎ豆まめ碱

羽はね扇おうぎ豆まめ碱
	IUPAC名めい; [(1R,9aR)-Octahydro-2H-quinolizin-1-yl]methane
识别
CAS号ごう	486-70-4
PubChem	91461
ChemSpider	82587
SMILES	OC[C@H]1[C@@H]2N(CCC1)CCCC2;
InChI	1/C10H19NO/c12-8-9-4-3-7-11-6-2-1-5-10(9)11/h9-10,12H,1-8H2/t9-,10+/m0/s1;
InChIKey	HDVAWXXJVMJBAR-VHSXEESVBK
3DMet	B04202
ChEBI	28012
KEGG	C10773
性せい质
化学かがく式しき	C10H19NO
摩ま尔质量りょう	169.26 g·mol−1
熔点	68—69 °C（154—156 °F；341—342 K）
沸点ふってん	269—270 °C（516—518 °F；542—543 K）
危险性せい
	GHS危险性せい符号ふごう;
GHS提示ていじ词	Warning
H-术语	H302, H312, H332
P-术语	P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P501
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

羽はね扇おうぎ豆まめ碱（英語えいご：lupinine），即そく(1R,9aR)-八はち氢-2H-喹嗪-1-甲きのえ醇あつし，是ぜ一いち种有ゆう机つくえ化合かごう物ぶつ，化学かがく式しき为C₁₀H₁₉NO。它可以三烷基硅氧基呋喃为原料合成得到。^[1]它和甲きのえ磺酰氯在ざい三さん乙おつ胺存在そんざい下か于二に氯甲烷中ちゅう反はん应，可か以得到いた羽はね扇おうぎ豆まめ碱甲磺酸酯。^[2]它和碘甲烷在ざい丙へい酮中ちゅう反はん应，可か以得到いたN-甲きのえ基はじめ羽はね扇おうぎ豆まめ碱鎓碘化物ぶつ。^[3]

参考さんこう文献ぶんけん[编辑]

^ Santos, Leonardo; Mirabal-Gallardo, Yaneris; Shankaraiah, Nagula; Simirgiotis, Mario. Short Total Synthesis of (-)-Lupinine and (-)-Epiquinamide by Double Mitsunobu Reaction. Synthesis (Georg Thieme Verlag KG). 2010-12-08, 2011 (01): 51–56. ISSN 0039-7881. doi:10.1055/s-0030-1258356.
^ Nurmaganbetov, Zhangeldy S.; Savelyev, Viktor A.; Gatilov, Yurii V.; Nurkenov, Oralgazy A.; Seidakhmetova, Roza B.; Shulgau, Zarina T.; Mukusheva, Gulim K.; Fazylov, Serik D.; Shults, Elvira E. Synthesis and analgesic activity of 1-[(1,2,3-triazol-1-yl)methyl]quinolizines based on the alkaloid lupinine. Chemistry of Heterocyclic Compounds (Springer Science and Business Media LLC). 2021, 57 (9): 911–919. ISSN 0009-3122. doi:10.1007/s10593-021-03000-7.
^ Fitch, Richard W.; Sturgeon, Gordon D.; Patel, Shaun R.; Spande, Thomas F.; Garraffo, H. Martin; Daly, John W.; Blaauw, Richard H. Epiquinamide: A Poison That Wasn’t from a Frog That Was. Journal of Natural Products (American Chemical Society (ACS)). 2009-02-06, 72 (2): 243–247. ISSN 0163-3864. doi:10.1021/np8005452.

[1] Santos, Leonardo; Mirabal-Gallardo, Yaneris; Shankaraiah, Nagula; Simirgiotis, Mario. Short Total Synthesis of (-)-Lupinine and (-)-Epiquinamide by Double Mitsunobu Reaction. Synthesis (Georg Thieme Verlag KG). 2010-12-08, 2011 (01): 51–56. ISSN 0039-7881. doi:10.1055/s-0030-1258356.

[2] Nurmaganbetov, Zhangeldy S.; Savelyev, Viktor A.; Gatilov, Yurii V.; Nurkenov, Oralgazy A.; Seidakhmetova, Roza B.; Shulgau, Zarina T.; Mukusheva, Gulim K.; Fazylov, Serik D.; Shults, Elvira E. Synthesis and analgesic activity of 1-[(1,2,3-triazol-1-yl)methyl]quinolizines based on the alkaloid lupinine. Chemistry of Heterocyclic Compounds (Springer Science and Business Media LLC). 2021, 57 (9): 911–919. ISSN 0009-3122. doi:10.1007/s10593-021-03000-7.

[3] Fitch, Richard W.; Sturgeon, Gordon D.; Patel, Shaun R.; Spande, Thomas F.; Garraffo, H. Martin; Daly, John W.; Blaauw, Richard H. Epiquinamide: A Poison That Wasn’t from a Frog That Was. Journal of Natural Products (American Chemical Society (ACS)). 2009-02-06, 72 (2): 243–247. ISSN 0163-3864. doi:10.1021/np8005452.

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