羽はね扇おうぎ豆まめ鹼

羽はね扇おうぎ豆まめ鹼
	IUPAC名めい; [(1R,9aR)-Octahydro-2H-quinolizin-1-yl]methane
識別しきべつ
CAS號ごう	486-70-4
PubChem	91461
ChemSpider	82587
SMILES	OC[C@H]1[C@@H]2N(CCC1)CCCC2;
InChI	1/C10H19NO/c12-8-9-4-3-7-11-6-2-1-5-10(9)11/h9-10,12H,1-8H2/t9-,10+/m0/s1;
InChIKey	HDVAWXXJVMJBAR-VHSXEESVBK
3DMet	B04202
ChEBI	28012
KEGG	C10773
性質せいしつ
化學かがく式しき	C10H19NO
摩ま爾なんじ質量しつりょう	169.26 g·mol−1
熔點	68—69 °C（154—156 °F；341—342 K）
沸點ふってん	269—270 °C（516—518 °F；542—543 K）
危險きけん性せい
	GHS危險きけん性せい符號ふごう;
GHS提示ていじ詞し	Warning
H-術語じゅつご	H302, H312, H332
P-術語じゅつご	P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P501
	若わか非ひ註明，所有しょゆう數すう據よりどころ均ひとし出自しゅつじ標準ひょうじゅん狀態じょうたい（25 ℃，100 kPa）下した。

羽はね扇おうぎ豆まめ鹼（英語えいご：lupinine），即そく(1R,9aR)-八はち氫-2H-喹嗪-1-甲きのえ醇あつし，是ぜ一いち種しゅ有機ゆうき化合かごう物ぶつ，化學かがく式しき為ためC₁₀H₁₉NO。它可以三烷基硅氧基呋喃為原料合成得到。^[1]它和甲きのえ磺酰氯在ざい三さん乙おつ胺存在そんざい下か於二に氯甲烷中ちゅう反應はんのう，可か以得到いた羽はね扇おうぎ豆まめ鹼甲磺酸酯。^[2]它和碘甲烷在ざい丙へい酮中ちゅう反應はんのう，可か以得到いたN-甲きのえ基はじめ羽はね扇おうぎ豆まめ鹼鎓碘化物ぶつ。^[3]

參考さんこう文獻ぶんけん

^ Santos, Leonardo; Mirabal-Gallardo, Yaneris; Shankaraiah, Nagula; Simirgiotis, Mario. Short Total Synthesis of (-)-Lupinine and (-)-Epiquinamide by Double Mitsunobu Reaction. Synthesis (Georg Thieme Verlag KG). 2010-12-08, 2011 (01): 51–56. ISSN 0039-7881. doi:10.1055/s-0030-1258356.
^ Nurmaganbetov, Zhangeldy S.; Savelyev, Viktor A.; Gatilov, Yurii V.; Nurkenov, Oralgazy A.; Seidakhmetova, Roza B.; Shulgau, Zarina T.; Mukusheva, Gulim K.; Fazylov, Serik D.; Shults, Elvira E. Synthesis and analgesic activity of 1-[(1,2,3-triazol-1-yl)methyl]quinolizines based on the alkaloid lupinine. Chemistry of Heterocyclic Compounds (Springer Science and Business Media LLC). 2021, 57 (9): 911–919. ISSN 0009-3122. doi:10.1007/s10593-021-03000-7.
^ Fitch, Richard W.; Sturgeon, Gordon D.; Patel, Shaun R.; Spande, Thomas F.; Garraffo, H. Martin; Daly, John W.; Blaauw, Richard H. Epiquinamide: A Poison That Wasn’t from a Frog That Was. Journal of Natural Products (American Chemical Society (ACS)). 2009-02-06, 72 (2): 243–247. ISSN 0163-3864. doi:10.1021/np8005452.

[1] Santos, Leonardo; Mirabal-Gallardo, Yaneris; Shankaraiah, Nagula; Simirgiotis, Mario. Short Total Synthesis of (-)-Lupinine and (-)-Epiquinamide by Double Mitsunobu Reaction. Synthesis (Georg Thieme Verlag KG). 2010-12-08, 2011 (01): 51–56. ISSN 0039-7881. doi:10.1055/s-0030-1258356.

[2] Nurmaganbetov, Zhangeldy S.; Savelyev, Viktor A.; Gatilov, Yurii V.; Nurkenov, Oralgazy A.; Seidakhmetova, Roza B.; Shulgau, Zarina T.; Mukusheva, Gulim K.; Fazylov, Serik D.; Shults, Elvira E. Synthesis and analgesic activity of 1-[(1,2,3-triazol-1-yl)methyl]quinolizines based on the alkaloid lupinine. Chemistry of Heterocyclic Compounds (Springer Science and Business Media LLC). 2021, 57 (9): 911–919. ISSN 0009-3122. doi:10.1007/s10593-021-03000-7.

[3] Fitch, Richard W.; Sturgeon, Gordon D.; Patel, Shaun R.; Spande, Thomas F.; Garraffo, H. Martin; Daly, John W.; Blaauw, Richard H. Epiquinamide: A Poison That Wasn’t from a Frog That Was. Journal of Natural Products (American Chemical Society (ACS)). 2009-02-06, 72 (2): 243–247. ISSN 0163-3864. doi:10.1021/np8005452.

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