N-甲きのえ基はじめ己おのれ胺

N-甲きのえ基はじめ己おのれ胺
识别
CAS号ごう	35161-70-7
性せい质
化学かがく式しき	C7H17N
摩ま尔质量りょう	115.22 g·mol−1
密度みつど	0.761 g·cm−3（20 °C）
沸点ふってん	135 °C（408 K）
	若わか非ひ注ちゅう明あかり，所有しょゆう数すう据すえ均ひとし出自しゅつじ标准状じょう态（25 ℃，100 kPa）下した。

N-甲きのえ基はじめ己おのれ胺是ぜ一いち种有ゆう机つくえ化合かごう物ぶつ，化学かがく式しき为C₇H₁₇N。它可由ゆかり甲きのえ胺、次じ氯酸钠和わ二甲基正己基硼（或ある三さん己おのれ基き硼^[3]）反はん应制得とく。^[4]它和亚硝酸しょうさん钠在ざい甲きのえ磺酸-氧化铝催化下か反はん应，可か以得到いたN-亚硝基もと-N-甲きのえ基はじめ己おのれ胺。^[5]它和溴化氰反はん应，可か以得到いたN-氰基-N-甲きのえ基はじめ己おのれ胺。^[6]

参考さんこう文献ぶんけん

^ Loffler, Karl. Formation of N-Alkyl Pyrrolidines. Berichte der Deutschen Chemischen Gesellschaft, 1910. 43: 2035-2048. ISSN 0365-9496.
^ Emmanuel Yankep, Henriette Kapnang, Georges Charles. Alkylaminomethylation d'organomagnesiens. Tetrahedron Letters. 1989-01, 30 (52): 7383–7384 [2022-02-22]. doi:10.1016/S0040-4039(00)70703-9. （原始げんし内容ないよう存そん档于2018-06-08）（英えい语）.
^ George W. Kabalka, Zhe Wang. Reaction of trialkylboranes with alkylamines: synthesis of dialkylamines. Organometallics. 1989-04, 8 (4): 1093–1095 [2022-02-22]. ISSN 0276-7333. doi:10.1021/om00106a034. （原始げんし内容ないよう存そん档于2022-02-22）（英えい语）.
^ George W. Kabalka, Zhe Wang. Preparation of Isomerically Pure Dialkylamines via the Reaction of Dimethylalkylboranes with Chloroalkylamine. Synthetic Communications. 1990-01, 20 (2): 231–237 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397919008052288 （英えい语）.
^ Khodabakhsh Niknam, Mohammad Ali Zolfigol. Alumina–Methanesulfonic Acid (AMA)/NaNO 2 as an Efficient Procedure for the Chemoselectivite N‐Nitrosation of Secondary Amines. Synthetic Communications. 2006-08, 36 (16): 2311–2319 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397910600639927 （英えい语）.
^ Toru Hashimoto, Satoshi Ishii, Reiko Yano, Hiroki Miura, Ken Sakata, Ryo Takeuchi. Iridium-Catalyzed [2+2+2] Cycloaddition of αあるふぁ,ωおめが-Diynes with Cyanamides. Advanced Synthesis & Catalysis. 2015-12-14, 357 (18): 3901–3916 [2022-02-22]. doi:10.1002/adsc.201500637. （原始げんし内容ないよう存そん档于2022-02-22）（英えい语）.

[1] Loffler, Karl. Formation of N-Alkyl Pyrrolidines. Berichte der Deutschen Chemischen Gesellschaft, 1910. 43: 2035-2048. ISSN 0365-9496.

[2] Emmanuel Yankep, Henriette Kapnang, Georges Charles. Alkylaminomethylation d'organomagnesiens. Tetrahedron Letters. 1989-01, 30 (52): 7383–7384 [2022-02-22]. doi:10.1016/S0040-4039(00)70703-9. （原始げんし内容ないよう存そん档于2018-06-08）（英えい语）.

[3] George W. Kabalka, Zhe Wang. Reaction of trialkylboranes with alkylamines: synthesis of dialkylamines. Organometallics. 1989-04, 8 (4): 1093–1095 [2022-02-22]. ISSN 0276-7333. doi:10.1021/om00106a034. （原始げんし内容ないよう存そん档于2022-02-22）（英えい语）.

[4] George W. Kabalka, Zhe Wang. Preparation of Isomerically Pure Dialkylamines via the Reaction of Dimethylalkylboranes with Chloroalkylamine. Synthetic Communications. 1990-01, 20 (2): 231–237 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397919008052288 （英えい语）.

[5] Khodabakhsh Niknam, Mohammad Ali Zolfigol. Alumina–Methanesulfonic Acid (AMA)/NaNO 2 as an Efficient Procedure for the Chemoselectivite N‐Nitrosation of Secondary Amines. Synthetic Communications. 2006-08, 36 (16): 2311–2319 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397910600639927 （英えい语）.

[6] Toru Hashimoto, Satoshi Ishii, Reiko Yano, Hiroki Miura, Ken Sakata, Ryo Takeuchi. Iridium-Catalyzed [2+2+2] Cycloaddition of αあるふぁ,ωおめが-Diynes with Cyanamides. Advanced Synthesis & Catalysis. 2015-12-14, 357 (18): 3901–3916 [2022-02-22]. doi:10.1002/adsc.201500637. （原始げんし内容ないよう存そん档于2022-02-22）（英えい语）.

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