钪
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此條 |
鈧是
鈧
性 质
[编辑]化学 性 质
[编辑]钪是银色
同位 素
[编辑]鈧
钪已发现
存在
[编辑]钪在
稳定
- 28Si + 17n → 45Sc(R-过程)
- 56Fe + p → 45Sc + 11C + n(
宇宙 射 线散裂 )
化合 物
[编辑]钪化
氧化物 和 氢氧化物
[编辑]钪的氧化
2O
3
3
- Sc(OH)
3 + 3 OH−
→ [Sc(OH)
6]3−
(钪酸根 ) - Sc(OH)
3 + 3 H+
+ 3 H
2O → [Sc(H
2O)
6]3+
卤化物
[编辑]钪的卤化
3
3
3
6]3−。
有 机 钪化合 物
[编辑]钪与环戊
2Cl]
2,以及
不 寻常氧化态
[编辑]
3
历史
[编辑]1869
生 产
[编辑]價格
[编辑]应用
[编辑]![](https://upload.wikimedia.org/wikipedia/commons/thumb/4/4f/Mig-29_on_landing.jpg/220px-Mig-29_on_landing.jpg)
钪用
健康 与 安全
[编辑]钪
参 见
[编辑]参考 文献
[编辑]- ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. Standard atomic weights of the elements 2021 (IUPAC Technical Report). Pure and Applied Chemistry. 2022-05-04. ISSN 1365-3075. doi:10.1515/pac-2019-0603 (
英 语). - ^ 2.0 2.1 McGuire, Joseph C.; Kempter, Charles P. Preparation and Properties of Scandium Dihydride. Journal of Chemical Physics. 1960, 33: 1584–1585. doi:10.1063/1.1731452.
- ^ 3.0 3.1 Smith, R. E. Diatomic Hydride and Deuteride Spectra of the Second Row Transition Metals. Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. 1973, 332 (1588): 113–127. doi:10.1098/rspa.1973.0015.
- ^ F. Geoffrey N. Cloke; Karl Khan & Robin N. Perutz.
η -Arene complexes of scandium(0) and scandium(II). J. Chem. Soc., Chem. Commun. 1991, (19): 1372–1373. doi:10.1039/C39910001372. - ^ IUPAC Recommendations, NOMENCLATURE OF INORGANIC CHEMISTRY
- ^ Mineral Commodity Summaries 2020 (PDF). US Geological Survey Mineral Commodities Summary 2020. US Geological Survey. [10 February 2020]. (
原始 内容 存 档 (PDF)于2021-05-09). - ^ "Scandium (页面
存 档备份,存 于互联网档案 馆)." Los Alamos National Laboratory. Retrieved 2013-07-17. - ^ 8.0 8.1 Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik. The NUBASE Evaluation of Nuclear and Decay Properties. Nuclear Physics A. 2003, 729 (1): 3–128 [2021-10-02]. Bibcode:2003NuPhA.729....3A. CiteSeerX 10.1.1.692.8504
. doi:10.1016/j.nuclphysa.2003.11.001. (
原始 内容 存 档于2021-11-04). - ^ Lide, David R. CRC Handbook of Chemistry and Physics
. Boca Raton: CRC Press. 2004: 4–28. ISBN 978-0-8493-0485-9.
- ^ Bernhard, F. Scandium mineralization associated with hydrothermal lazurite-quartz veins in the Lower Austroalpie Grobgneis complex, East Alps, Austria. Mineral Deposits in the Beginning of the 21st Century. Lisse: Balkema. 2001. ISBN 978-90-265-1846-1.
- ^ 11.0 11.1 Kristiansen, Roy. Scandium – Mineraler I Norge (PDF). Stein. 2003: 14–23 [2021-10-02]. (
原始 内容 存 档 (PDF)于2021-02-28) (挪威语). - ^ von Knorring, O.; Condliffe, E. Mineralized pegmatites in Africa. Geological Journal. 1987, 22: 253. doi:10.1002/gj.3350220619.
- ^ Cameron, A.G.W. Stellar Evolution, Nuclear Astrophysics, and Nucleogenesis (PDF). CRL-41. June 1957 [2021-10-02]. (
原始 内容 存 档 (PDF)于2021-08-19). - ^ Cotton, Simon. Lanthanide and actinide chemistry. John Wiley and Sons. 2006: 108– [2011-06-23]. ISBN 978-0-470-01006-8. (
原始 内容 存 档于2021-08-21). - ^ Christensen, A. Nørlund; Stig Jorgo Jensen. Hydrothermal Preparation of
α -ScOOH and ofγ -ScOOH. Crystal Structure ofα -ScOOH. Acta Chemica Scandinavica. 1967, 21: 1121–126. doi:10.3891/acta.chem.scand.21-0121.
- ^ Shapiro, Pamela J.; et al. Model Ziegler-Natta
α -Olefin Polymerization Catalysts Derived from [{(η 5−C
5Me
4)SiMe
2(η 1−NCMe
3)}(PMe
3)Sc(μ 2−H)]
2 and [{(η 5−C
5Me
4)SiMe
2(η 1−NCMe
3)}Sc(μ 1−CH
2CH
2CH
3)]
2. Synthesis, Structures and Kinetic and Equilibrium Investigations of the Catalytically active Species in Solution. Journal of the American Chemical Society. 1994, 116 (11): 4623. doi:10.1021/ja00090a011. - ^ Corbett, J. D. Extended metal-metal bonding in halides of the early transition metals. Accounts of Chemical Research. 1981, 14 (8): 239–246. doi:10.1021/ar00068a003.
- ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
- ^ Polly L. Arnold; F. Geoffrey; N. Cloke; Peter B. Hitchcock & John F. Nixon. The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring. Journal of the American Chemical Society. 1996, 118 (32): 7630–7631. doi:10.1021/ja961253o.
- ^ F. Geoffrey N. Cloke; Karl Khan & Robin N. Perutz.
η -Arene complexes of scandium(0) and scandium(II). Journal of the Chemical Society, Chemical Communications. 1991, (19): 1372–1373. doi:10.1039/C39910001372. - ^ Ana Mirela Neculai; Dante Neculai; Herbert W. Roesky; Jörg Magull; Marc Baldus; et al. Stabilization of a Diamagnetic ScIBr Molecule in a Sandwich-Like Structure. Organometallics. 2002, 21 (13): 2590–2592. doi:10.1021/om020090b.
- ^ Polly L. Arnold; F. Geoffrey; N. Cloke & John F. Nixon. The first stable scandocene: synthesis and characterisation of bis(
η -2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II). Chemical Communications. 1998, (7): 797–798. doi:10.1039/A800089A. - ^ Nilson, Lars Fredrik. Sur l'ytterbine, terre nouvelle de M. Marignac. Comptes Rendus. 1879, 88: 642–647 [2019-06-26]. (
原始 内容 存 档于2021-04-28) (法 语). - ^ Nilson, Lars Fredrik. Ueber Scandium, ein neues Erdmetall. Berichte der deutschen chemischen Gesellschaft. 1879, 12 (1): 554–557. doi:10.1002/cber.187901201157 (
德 语). - ^ Fischer, Werner; Brünger, Karl; Grieneisen, Hans. Über das metallische Scandium. Zeitschrift für anorganische und allgemeine Chemie. 1937, 231 (1–2): 54–62. doi:10.1002/zaac.19372310107 (
德 语). - ^ Mineral Commodity Summaries. USGS. [2020-09-13]. (
原始 内容 存 档于2018-06-29). - ^ Ahmad, Zaki. The properties and application of scandium-reinforced aluminum. JOM. 2003, 55 (2): 35. Bibcode:2003JOM....55b..35A. doi:10.1007/s11837-003-0224-6.
- ^ Horovitz, Chaim T.; Birmingham, Scott D. Biochemistry of Scandium and Yttrium. Springer. 1999 [2021-10-02]. ISBN 978-0-306-45657-2. (
原始 内容 存 档于2022-01-02). - ^ Haley, Thomas J.; Komesu, L.; Mavis, N.; Cawthorne, J.; Upham, H. C. Pharmacology and toxicology of scandium chloride. Journal of Pharmaceutical Sciences. 1962, 51 (11): 1043–5. PMID 13952089. doi:10.1002/jps.2600511107.
外部 連結
[编辑]元素 钪在洛 斯阿拉 莫斯国家 实验室 的 介 紹(英文 )- EnvironmentalChemistry.com —— 钪(
英文 ) 元素 钪在 The Periodic Table of Videos(諾 丁 漢 大學 )的 介 紹(英文 )元素 钪在Peter van der Krogt elements site的 介 紹(英文 )- WebElements.com – 钪(
英文 )
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IA 1 |
IIA 2 |
IIIB 3 |
IVB 4 |
VB 5 |
VIB 6 |
VIIB 7 |
VIIIB 8 |
VIIIB 9 |
VIIIB 10 |
IB 11 |
IIB 12 |
IIIA 13 |
IVA 14 |
VA 15 |
VIA 16 |
VIIA 17 |
VIIIA 18 | ||||||||||||||||||||
1 | H | He | |||||||||||||||||||||||||||||||||||
2 | Li | Be | B | C | N | O | F | Ne | |||||||||||||||||||||||||||||
3 | Na | Mg | Al | Si | P | S | Cl | Ar | |||||||||||||||||||||||||||||
4 | K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr | |||||||||||||||||||
5 | Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe | |||||||||||||||||||
6 | Cs | Ba | La | Ce | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | Po | At | Rn | |||||
7 | Fr | Ra | Ac | Th | Pa | U | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||||
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