ジエチル亜鉛
ジエチル Diethylzinc | |
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diethylzinc | |
DEZ | |
CAS |
557-20-0 ![]() |
| |
(C2H5)2Zn | |
モル |
123.50 g/mol |
1.205 g/mL | |
-28℃ | |
117℃ | |
ジメチル | |
ジエチル
合成
[1848
反応
[ジエチル
構造
[ジエチル
用途
[安全 性
[脚注
[- ^ E. Frankland (1850). “On the isolation of the organic radicals”. Quarterly Journal of the Chemical Society 2: 263. doi:10.1039/QJ8500200263.
- ^ E. Frankland, B. F. Duppa (1864). “On a new reaction for the production of the zinc-compounds of the alkyl-radical”. Journal of the Chemical Society 17: 29–36. doi:10.1039/JS8641700029.
- ^ C. R. Noller (1943). "Diethyl Zinc". Organic Syntheses (
英語 ).; Collective Volume, vol. 2, p. 184 - ^ Masato Kitamura, Hiromasa Oka, Seiji Suga, and Ryoji Noyori (2004). "Catalytic Enantioselective Addition of Dialkylzincs to Aldehydes Using (2S)-(−)-3-exo-(Dimethylamino)isoborneol [(2S)-DAIB]: (S)-1-Phenyl-1-propanol". Organic Syntheses (
英語 ).; Collective Volume, vol. 10, p. 635 - ^ Jean-Nicolas Desrosiers, Alexandre Côté, Alessandro A. Boezio, and André B. Charette (2005). "Preparation of Enantiomerically Enriched (1S)-1-Phenylpropan-1-amine Hydrochloride by a Catalytic Addition of Diorganozinc Reagents to Imines". Organic Syntheses (
英語 ). 83: 5. - ^ André B. Charette and Hélène Lebel (2004). "(2S,3S)-(+)-(3-Phenylcyclopropyl)methanol". Organic Syntheses (
英語 ).; Collective Volume, vol. 10, p. 613 - ^ Yoshihiko Ito, Shotaro Fujii, Masashi Nakatuska, Fumio Kawamoto, and Takeo Saegusa (1988). "One-Carbon Ring Expansion of Cycloalkanones to Conjugated Cycloalkenones: 2-Cyclohepten-1-one". Organic Syntheses (
英語 ).; Collective Volume, vol. 6, p. 327 - ^ John Bacsa; Felix Hanke; Sarah Hindley; Rajesh Odedra; George R. Darling; Anthony C. Jones; Alexander Steiner (2011). “The Solid State Structures of Dimethylzinc and Diethylzinc”. Angewandte Chemie International Edition 50: 11685–11687. doi:10.1002/anie.201105099.
- ^ A. Haaland; J. C. Green; G. S. McGrady; A. J. Downs; E. Gullo; M. J. Lyall; J. Timberlake; A. V. Tutukin et al. (2003). “The length, strength and polarity of metal–carbon bonds: dialkylzinc compounds studied by density functional theory calculations, gas electron diffraction and photoelectron spectroscopy”. Dalton Transactions: 4356–4366. doi:10.1039/B306840B.
- ^ Nicholson Baker (2002). Double Fold: Libraries and the Assault on Paper. Vintage. ISBN 0375726217
- ^
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