碲酮

碲酮是これ酮的てき氧被碲取と代だい得え到いた的てき类似物ぶつ，它的稳定性せい很差，需要じゅよう借か助じょ于位くらい阻效应和わ电子效こう应来らい使つかい其稳定じょう。^[1]1,1,3,3-四よん甲きのえ基はじめ茚满-2-碲酮（CAS号ごう：150194-22-2）是ぜ发现的てき第だい一个在溶液中稳定的碲酮，^[2]它也是ぜ第だい一个被分离出来的碲酮，以绿色しょく针状晶あきら体からだ的てき形式けいしき存在そんざい。^[3]双そう(二に茂しげる铁)甲きのえ酮和碲化二に(二に甲きのえ基はじめ铝)反はん应，可か以得到いた蓝色的てき双そう(二に茂しげる铁)碲酮。^[4]

参考さんこう文献ぶんけん[编辑]

^ Okazaki, R.; Tokitoh, N. Heavy ketones, the heavier element congeners of a ketone. Accounts of Chemical Research. 2000, 33 (9): 625–630. PMID 10995200. doi:10.1021/ar980073b.
^ Minoura, Mao; Kawashima, Takayuki; Okazaki, Renji. 1,1,3,3-Tetramethylindantellone, the first telluroketone stable in solution. Journal of the American Chemical Society. 1993, 115 (15): 7019–7020. ISSN 0002-7863. doi:10.1021/ja00068a088.
^ Minoura, Mao; Kawashima, Takayuki; Okazaki*, Renji. The First Isolation of a Telluroketone and Its Reversible Dimerization. Tetrahedron Letters. 1997, 38 (14): 2501–2504. ISSN 0040-4039. doi:10.1016/S0040-4039(97)00377-8.
^ Denifl, Peter; Bildstein, Benno. Synthese und reaktivität von diferrocenyl-thio-,-seleno- und -telluro-keton. Journal of Organometallic Chemistry. 1993, 453 (1): 53–59. ISSN 0022-328X. doi:10.1016/0022-328X(93)80326-7.

拓つぶせ展てん阅读[编辑]

Francesco A. Devillanova. Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium. Royal Society of Chemistry. 2007. ISBN 978-0-85404-366-8.

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[Oka-1] Okazaki, R.; Tokitoh, N. Heavy ketones, the heavier element congeners of a ketone. Accounts of Chemical Research. 2000, 33 (9): 625–630. PMID 10995200. doi:10.1021/ar980073b.

[2] Minoura, Mao; Kawashima, Takayuki; Okazaki, Renji. 1,1,3,3-Tetramethylindantellone, the first telluroketone stable in solution. Journal of the American Chemical Society. 1993, 115 (15): 7019–7020. ISSN 0002-7863. doi:10.1021/ja00068a088.

[3] Minoura, Mao; Kawashima, Takayuki; Okazaki*, Renji. The First Isolation of a Telluroketone and Its Reversible Dimerization. Tetrahedron Letters. 1997, 38 (14): 2501–2504. ISSN 0040-4039. doi:10.1016/S0040-4039(97)00377-8.

[4] Denifl, Peter; Bildstein, Benno. Synthese und reaktivität von diferrocenyl-thio-,-seleno- und -telluro-keton. Journal of Organometallic Chemistry. 1993, 453 (1): 53–59. ISSN 0022-328X. doi:10.1016/0022-328X(93)80326-7.

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